Synthesis of Dihydropyrans and Dihydrofurans via Radical Cyclization of Unsaturated Alcohols and 1 3 Dicarbonyl Compounds
Yazarlar (5)
Dr. Öğr. Üyesi Hakan ASLAN Sinop Üniversitesi, Türkiye
Deniz E. Akpbox Drawings Light Down
Ankara Üniversitesi, Türkiye
Ankara Üniversitesi, Türkiye
Atilla Öktemer
Ankara Üniversitesi, Türkiye
Ankara Üniversitesi, Türkiye
Dr. Öğr. Üyesi Mehtap Yakut Ankara Üniversitesi, Türkiye
Oǧuzhan Alagöz
Afyon Kocatepe Üniversitesi, Türkiye
Afyon Kocatepe Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Helvetica Chimica Acta (Q3) | ||
| Dergi ISSN | 0018-019X Dergi Bilgileri (2014) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Ingilizce | Basım Tarihi | 05-2014 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-05-2014 |
| Cilt / Sayı / Sayfa | 97 / 5 / 652–663 | DOI | 10.1002/hlca.201300229 |
| Makale Linki | http://doi.wiley.com/10.1002/hlca.201300229 | ||
| UAK Araştırma Alanları |
Organik Kimya
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| Özet |
| The oxidative cyclization reactions of 1,3‐dicarbonyl compounds 1a–1c and α,β‐unsaturated alcohols 2a–2f with Mn(OAc)3 were performed, leading to dihydrofurans. Treatment of 1a and 1b with 2‐methylbut‐3‐en‐2‐ol (2a) gave dihydrofurans 3aa and 3ba, and dihydropyrans 4aa and 4ba, as unexpected products. While the reaction of 2‐methylbut‐3‐yn‐2‐ol (2b) with acetylacetone (1b) yielded a bifuran, ethyl acetoacetate (1a) led to a mixture of furan, bifuran, and salicylate derivatives. Besides, surprisingly, styryl‐substituted dihydrofurans were obtained from the reactions of 1,3‐dicarbonyl compounds and (3E)‐2,4‐diphenylbut‐3‐en‐2‐ol. The reaction mechanisms were proposed for the formation of the different products, considering intermediates in these reaction mixtures. |
| Anahtar Kelimeler |
| Cyclization reactions | dihydro- | Furans | Manganese(III) acetate | Pyrans |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 6 |
| Scopus | 8 |
| Google Scholar | 12 |