Combined Experimental And Theoretical Study Of The Novel Ferrocene Derivatives And Examining The Effect Of E-Z Stereoisomerism On Their Optical Properties
Yazarlar (5)
Dr. Öğr. Üyesi Hakan ASLAN Sinop Üniversitesi, Türkiye
Dr. Öğr. Üyesi Gülbin Kurtay Ankara Üniversitesi, Türkiye
Doç. Dr. Adem Korkmaz Muş Alparslan Üniversitesi, Türkiye
Prof. Dr. Adnan Çetin Muş Alparslan Üniversitesi, Türkiye
Atilla Öktemer
Ankara Üniversitesi, Türkiye
Ankara Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Optical Materials (Q2) | ||
| Dergi ISSN | 0925-3467 Dergi Bilgileri (2019) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | Ingilizce | Basım Tarihi | 03-2019 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-03-2019 |
| Cilt / Sayı / Sayfa | 89 / 1 / 452–459 | DOI | 10.1016/j.optmat.2019.01.072 |
| Makale Linki | http://dx.doi.org/10.1016/j.optmat.2019.01.072 | ||
| UAK Araştırma Alanları |
Organik Kimya
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| Özet |
| Herein, we present the primary results on two valuable E-Z stereoisomers containing ferrocene scaffold [(E)-5,5-dimethyl-3-oxo-2-(2-phenyl-2-ferrocenyl-vinyl)cyclohex-1-en-1-yl acetate (E-FerCycAc) and its Z-stereoisomer (Z-FerCycAc)]. These compounds were both prepared from 1-phenylvinyl-ferrocene and 5,5-dimethyl-1,3-cyclohexanedione under catalysis of manganese(III) acetate according to the radical addition mechanism. The prominent spectroscopic data of the target stereoisomers were provided by FT-IR, LC-MS, 1H NMR, 13C NMR techniques, and their stereochemical identification was made primarily by NOESY analysis. The corresponding data (absorbance, transmittance and optical and transport energy gap) were collected from UV–vis studies. The optical properties of the glass slides coated with E-FerCycAc and Z-FerCycAc films were examined and consequently, the optical and transport energy … |
| Anahtar Kelimeler |
| DFT | E-Z stereoisomerism | Ferrocene derivatives | Film coating | Optical conductivity |
Science Direct
Combined Experimental And Theoretical Study Of The Novel Ferrocene Derivatives And Examining The Effect Of E-Z Stereoisomerism On Their Optical Properties
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 2 |
| Scopus | 2 |
| Google Scholar | 2 |