Synthesis, spectral, thermal and structural characterization of two complexes containing [N-(2-hydroxyethyl)-ethylenediamine] with carboxylate
Yazarlar (2)
Doç. Dr. Tuğba AK KİRBAŞ Sinop Üniversitesi, Türkiye
Hümeyra Paşaoǧlu
Ondokuz Mayis University Faculty of Science And Arts, Türkiye
Ondokuz Mayis University Faculty of Science And Arts, Türkiye
| Bildiri Türü | Tebliğ/Bildiri | Bildiri Dili | İngilizce |
| Bildiri Alt Türü | Tam Metin Olarak Yayınlanan Tebliğ (Uluslararası Kongre/Sempozyum) | ||
| Bildiri Niteliği | Web of Science Kapsamındaki Kongre/Sempozyum | ||
| DOI Numarası | 10.1063/1.5026006 | ||
| Kongre Adı | TURKISH PHYSICAL SOCIETY 33rd INTERNATIONAL PHYSICS CONGRESS | ||
| Kongre Tarihi | 06-09-2017 / 10-09-2017 | ||
| Basıldığı Ülke | Türkiye | Basıldığı Şehir | Muğla |
| Bildiri Linki | http://dx.doi.org/10.1063/1.5026006 | ||
| UAK Araştırma Alanları |
Atom, Molekül ve Lazer Fiziği
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| Özet |
| Compounds based on the [Zn(hydet-en)2].(tpht).(H2O) (1) (tpht=dianion of terephthalic acid, hydet-en=N-(2-hydroxyethyl)ethylenediamine) has been synthesized which is characterized by single crystal X-ray determination, IR and thermal analysis. In 1, the Zinc(II) ion is six-coordinated that sandwiched by two hydet-en ligands which lies each hydeten ligand adopts a tripodal conformation and acts as tridentate ligand, carboxylate is uncoordinated. The coordination monomer is connected by C(13) chains and linear chains are connected by O-H···O H-bonds formed by DA:AD type 4 organization of aqua ligands and tpa2− ions resulting in synthons to 3D structure. The FT-IR investigation of the complex were performed within the mid-IR region, mainly focusing on the characteristic vibrations of its free state and ligand behaviour in the case of complex formation. Thermal behaviours of 1 were followed using TG … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 2 |
| Scopus | 1 |
| Google Scholar | 1 |