Synthesis, crystal structure, spectroscopic (FT-IR, UV--Vis, EPR) and Hirshfeld surface analysis studies of Zn(II)-benzoate coordination dimer
Yazarlar (1)
Doç. Dr. Tuğba AK KİRBAŞ Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2021) | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2021 |
| Cilt / Sayı / Sayfa | 1223 / 1 / 128943–0 | DOI | 10.1016/j.molstruc.2020.128943 |
| Makale Linki | https://www.sciencedirect.com/science/article/abs/pii/S0022286020312680 | ||
| UAK Araştırma Alanları |
Atom, Molekül ve Lazer Fiziği
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| Özet |
| Mixed ligand coordination dimer [Zn2(BA)4(NA)2].(BAH), (BAH=Benzoic acid, NA=nicotinamide), synthesized and its supramolecular architecture was investigated. The structural properties of the coordination dimer were characterized by X-ray diffraction (XRD), elemental analysis, spectroscopic methods (EPR, UV--Vis and FT-IR), thermogravimetric analysis and Hirshfeld surface analysis. The complex crystallized in the monoclinic crystal system and the P21/c space group. Two benzoate anions bind to zinc metals as chelates, while the other two-benzoate anions bridge between two metals. The coordinate environment of the Zn1 atom has a nearly ideal square pyramidal geometry and the τ factor defined by Addison is 0.09. The coordination environment of the Zn2 atom has an extremely distorted (4 + 1) pseudo-square pyramidal geometry and the τ factor was found to be 0.35. Hydrogen bonds and π⋯π weak ... |
| Anahtar Kelimeler |
| Benzoic acid | Dimer coordination | Hirshfeld surface analysis | Single crystal XRD | Spectroscopic characterization |
Science Direct
Synthesis, crystal structure, spectroscopic (FT-IR, UV--Vis, EPR) and Hirshfeld surface analysis studies of Zn(II)-benzoate coordination dimer
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 7 |
| Scopus | 7 |
| Google Scholar | 8 |