Investigation of structural, spectral and thermal properties of one-dimensional polymer containing pyromellitic acid and isonicotinamide
Yazarlar (3)
Doç. Dr. Tuğba AK KİRBAŞ Sinop Üniversitesi, Türkiye
Doç. Dr. Filiz Öztürk Ondokuz Mayis Üniversitesi, Türkiye
Hümeyra Paşaoğlu
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2019) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2019 |
| Cilt / Sayı / Sayfa | 1176 / 1 / 685–694 | DOI | 10.1016/j.molstruc.2018.08.109 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S0022286018310585 | ||
| UAK Araştırma Alanları |
Atom, Molekül ve Lazer Fiziği
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| Özet |
| The coordination polymer with mixed ligand [Cu2(H2O)2 (pm) (ina)2]n.3nH2O (pm = tetraanion of pyromellitic acid, ina = isonicotinamide) was studied mostly on its supramolecular architecture. Single crystals were synthesized and structural properties of the 1D polymer were characterized by Single Crystal X-ray diffraction (SCXRD), different spectroscopic methods (Infrared (IR) spectroscopy, UV--Vis spectroscopy and EPR spectroscopy), Thermal and Elemental analysis. It has been observed that complex has crystallized in the monoclinic space group P21/c. The geometric environment of Cu(II) ion is five-coordinated in slightly distorted square pyramidal geometry and τ value have found 0.13. The pyromellitate ligands connecting the metal centers act as bridge and form 1D polymer chains of 2,4 ribbon type [1]. The ladder-like polymer is connected by Osingle bondH⋯O and Nsingle bondH⋯O hydrogen bonds ... |
| Anahtar Kelimeler |
| Coordination polymer | Pyromellitic acid | Single crystal X-ray diffraction | Spectroscopic methods |
Science Direct
Investigation of structural, spectral and thermal properties of one-dimensional polymer containing pyromellitic acid and isonicotinamide
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 3 |
| Scopus | 3 |
| Google Scholar | 5 |