Spectroscopic, structural characterization and magnetic studies of Cu(II)-sulfathiazole complex with 1,10-Phenanthroline and N-(2-hydroxyethyl)-Ethylenediamine ligands
Yazarlar (3)
Doç. Dr. Filiz Öztürk Ondokuz Mayıs Üniversitesi, Türkiye
Doç. Dr. Tuğba AK KİRBAŞ Sinop Üniversitesi, Türkiye
Prof. Dr. Ahmet Hilmi Çon Ondokuz Mayıs Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2020) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2020 |
| Cilt / Sayı / Sayfa | 1202 / 1 / 127220–0 | DOI | 10.1016/j.molstruc.2019.127220 |
| Makale Linki | https://doi.org/10.1016/j.molstruc.2019.127220 | ||
| UAK Araştırma Alanları |
Atom, Molekül ve Lazer Fiziği
Spektroskopi
|
||
| Özet |
| Abstract Cu (II)-sulfathiazole (Hstz: 4-amino-N-(1, 3-thiazol-2-yl) benzene sulfonamide) complex with phen (1, 10-Phenanthroline) and Hydeten (N-(2-hydroxyethyl)-Ethylenediamine) has been synthesized and characterized by single crystal X-ray diffraction, IR, EPR and UV--Vis spectroscopy, thermal analysis. The [Cu (stz)(Hydeten)(Phen)].(stz)(Phen) complex crystallizes in the orthorhombic space group Pca2 1, Z= 4. The sulfathiazole anion acts as a monodentate ligand through the thiadiazole N atom contiguous to the deprotonated sulfonamide group. The trigonality factor (τ=(β-α)/60) value of the copper complex is 0.14 and this value expresses having slightly distorted square pyramidal environment of the Cu (II) ions coordination. The powder EPR spectra of Cu (II) complex were recorded at room temperature and liquid nitrogen temperature. The EPR spectral analysis has led to that the ground state of the ... |
| Anahtar Kelimeler |
| Antimicrobial activity | EPR | FT-IR spectroscopy | Sulfathiazole | X-ray crystal structure |
Science Direct
Spectroscopic, structural characterization and magnetic studies of Cu(II)-sulfathiazole complex with 1,10-Phenanthroline and N-(2-hydroxyethyl)-Ethylenediamine ligands
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 4 |
| Scopus | 5 |
| Google Scholar | 7 |