The prototropic tautomerism and substituent effect through strong electron withdrawing group in E 5 diethylamino 2 3 nitrophenylimino methyl phenol
Yazarlar (4)
Prof. Dr. Çiğdem ALBAYRAK KAŞTAŞ Sinop Üniversitesi, Türkiye
Prof. Dr. Gokhan Kaştaş Sinop Üniversitesi, Türkiye
Mustafa Odabaşoǧlu
Pamukkale Üniversitesi, Türkiye
Pamukkale Üniversitesi, Türkiye
Rene Frank Universität Leipzig, Almanya
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy (Q2) | ||
| Dergi ISSN | 1386-1425 Dergi Bilgileri (2013) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2013 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-10-2013 |
| Cilt / Sayı / Sayfa | 114 / 1 / 205–213 | DOI | 10.1016/j.saa.2013.05.044 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S1386142513005337 | ||
| UAK Araştırma Alanları |
Organik Kimya
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| Özet |
| The prototropic tautomerism in o-Hydroxy Schiff bases results in two forms called phenol-imine and keto-amine. The preference of a particular form by the compound changes in the solid and solvent media. The choice can also be regulated by a substituent with a different electron-donating or withdrawing group. In the present study, the above-mentioned factors are considered in the investigation of (E)-5-(diethylamino)-2-[(3-nitrophenylimino)methyl]phenol compound (an o-Hydroxy Schiff basis) by experimental (XRD, FT-IR and UV–vis) and computational (DFT and TD-DFT) methods. The results show that the title compound adopts only phenol-imine form in the solid and solvent media. This was attributed to the substituent effect through strong electron-withdrawing nitro group. |
| Anahtar Kelimeler |
| Computational study | DFT | FT-IR | Intramolecular proton transfer | Schiff base | UV-vis |
Science Direct
The prototropic tautomerism and substituent effect through strong electron withdrawing group in E 5 diethylamino 2 3 nitrophenylimino methyl phenol
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 24 |
| Google Scholar | 26 |