Probing the compound E 2 4 bromophenylimino methyl 6 ethoxyphenol mainly from the point of tautomerism in solvent media and the solid state by experimental and computational methods
Yazarlar (4)
Prof. Dr. Çiğdem ALBAYRAK KAŞTAŞ Sinop Üniversitesi, Türkiye
Gökhan Kata
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
Mustafa Odabaolu
Pamukkale Üniversitesi, Türkiye
Pamukkale Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2011) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2011 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-08-2011 |
| Cilt / Sayı / Sayfa | 1000 / 1 / 162–170 | DOI | 10.1016/j.molstruc.2011.06.018 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S0022286011004911 | ||
| UAK Araştırma Alanları |
Organik Kimya
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| Özet |
| In this study, (E)-2-[(4-bromophenylimino)methyl]-6-ethoxyphenol compound was investigated by mainly focusing on stacking interactions assembling the supramolecular network of the compound and on tautomerism in solvent media and in the solid state. In doing so, the molecular structure and spectroscopic properties of (E)-2-[(4-bromophenylimino)methyl]-6-ethoxyphenol were experimentally characterized by X-ray diffraction, FT-IR, NMR and UV/Vis spectroscopic techniques and computationally by DFT method. The X-ray diffraction and FT-IR analyses of the title compound reveal the existence of enol form in the solid state. The non-covalent CH⋯π and inter-molecular hydrogen bonding interactions assemble the supramolecular structure of the title compound by forming 4-connected (4,4)-net in Wells nomenclature. The dependence of tautomerism on solvent types was studied on the basis of UV/Vis spectra … |
| Anahtar Kelimeler |
| DFT | Inter-molecular hydrogen bond | Intra-molecular hydrogen bond | Schiff base | Tautomerism | TD-DFT |