An intermediate structure trapped in solid state tautomerization process of E 4 4 chlorophenylimino methyl benzene 1 2 3 trio
Yazarlar (5)
Prof. Dr. Hasan Karabiyik Dokuz Eylül Üniversitesi, Türkiye
Nazan Ocak-Iskeleli
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
Hande Petek
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
Prof. Dr. Çiğdem ALBAYRAK KAŞTAŞ Ondokuz Mayis Üniversitesi, Türkiye
Erbil Aǧar
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2008) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2008 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-02-2008 |
| Cilt / Sayı / Sayfa | 873 / 1 / 130–136 | DOI | 10.1016/j.molstruc.2007.03.017 |
| Makale Linki | http://apps.webofknowledge.com/full_record.do?product=UA&search_mode=GeneralSearch&qid=2&SID=V1bfAHcU4oy4oWDgwY5&page=2&doc=76&cacheurlFromRightClick=no | ||
| UAK Araştırma Alanları |
Organik Kimya
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| Özet |
| An intermediate structure between the benzenoid and cis-quinoid form of the title compound was trapped in solid-state tautomerization with the aid of OH⋯O type intermolecular H-bonds leading to multi-point self-recognition. X-ray crystallographic study reveals that an interesting extended structure, H-bonded polymeric chain, is formed by linking pseudocyclic centrosymmetric R22(10) supramolecular synthons between the Cs symmetry monomer units. In order to better understand structural features in solid state, ab initio quantum chemical calculations at level of RHF/6-31G∗ were performed in both gas-phase and the extended structure containing five dimers. The results from the computational studies suggest that the gas-phase conformation of the title compound that closely matches the crystal structure corresponds to a local energy minimum between its benzenoid and cis-quinoid form and the OH⋯O type … |
| Anahtar Kelimeler |
| Benzenoid | Quinoid | Schiff base | Synthon | Tautomerization |
Science Direct
An intermediate structure trapped in solid state tautomerization process of E 4 4 chlorophenylimino methyl benzene 1 2 3 trio
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 44 |
| Scopus | 44 |
| Google Scholar | 50 |