Electrochemical and Spectroscopic Study of 4 Phenyldiazenyl 2 tris hydroxymethyl methyl aminomethylene cyclohexa 3 5 dien 1 2H one Mechanism of the Azo and Imine Electroreduction
Yazarlar (4)
Semiha Çakir Gazi Üniversitesi, Türkiye
Prof. Dr. Ender Biçer Ondokuz Mayis Üniversitesi, Türkiye
Mustafa Odabaşoǧlu
Ondokuz Mayis Üniversitesi, Türkiye
Prof. Dr. Çiğdem ALBAYRAK KAŞTAŞ Ondokuz Mayis Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of the Brazilian Chemical Society (Q2)
Dergi ISSN 0103-5053 Dergi Bilgileri (2005)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 08-2005
Kabul Tarihi Yayınlanma Tarihi 01-08-2005
Cilt / Sayı / Sayfa 16 / 4 / 711–717 DOI 10.1590/S0103-50532005000500005
Makale Linki https://www.scielo.br/j/jbchs/a/dTDyr6GVLnbfYXCJfhdSSsf/?lang=en&format=pdf
UAK Araştırma Alanları
Organik Kimya
Özet
Newly synthesized 4-(phenyldiazenyl)-2-{[tris (hydroxymethyl) methyl] aminomethylene} cyclohexa-3, 5-dien-1 (2H)-one was characterized by elemental analysis, FT-IR, NMR, electronic spectra, voltammetry. Tautomeric equilibrium of 4-(phenyldiazenyl)-2-{[tris (hydroxymethyl) methyl] aminomethylene} cyclohexa-3, 5-dien-1 (2H)-one in DMSOd is supported by 1H NMR data. The nature of electrochemical process of 4-(phenyldiazenyl)-2-{[tris (hydroxymethyl) methyl] aminomethylene} cyclohexa-3, 5-dien-1 (2H)-one in Britton-Robinson buffer (pH 2-9) was studied on the HMDE by square-wave (SWV), adsorptive stripping square-wave (AdSWV) and cyclic voltammetry (CV). The electrochemical parameters (Ip/Ep, Ip/vp, Ip/pH, Ip/tacc) of the compound were determined.© 2005 Sociedade Brasileira de Química.
Anahtar Kelimeler
4-(phenyldiazenyl)-2-{[tris(hydroxymethyl)methyl]aminomethylene} cyclohexa-3,5-dien-1(2H)-one | Electronic spectra | FT-IR | Voltammetry