Cu(II) complex with thiosemicarbazone of glyoxylic acid as an anion ligand in a polymeric structure

Huseynova, Mansura Teyfur; Aliyeva, Mahizar Nacaf; Medjidov, Ajdar Akber; ŞAHİN, ONUR; Yalçın, Bahattin

doi:10.1016/j.molstruc.2018.08.090

Cu(II) complex with thiosemicarbazone of glyoxylic acid as an anion ligand in a polymeric structure

Yazarlar (5)

Mansura Teyfur Huseynova
Azerbaijan National Academy Of Sciences, Azerbaycan

Mahizar Nacaf Aliyeva
Azerbaijan National Academy Of Sciences, Azerbaycan

Ajdar Akber Medjidov Azerbaijan National Academy Of Sciences, Azerbaycan

Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye

Prof. Dr. Bahattin Yalçın Marmara Üniversitesi, Türkiye

Makale Türü	Diğer (Teknik, not, yorum, vaka takdimi, editöre mektup, özet, kitap krıtiği, araştırma notu, bilirkişi raporu ve benzeri) (SCI, SSCI, AHCI, SCI-Exp dergilerinde yayınlanan teknik not, editöre mektup, tartışma, vaka takdimi ve özet türünden makale)
Dergi Adı	Journal of Molecular Structure (Q3)
Dergi ISSN	0022-2860 Dergi Bilgileri (2019)
Makale Dili	İngilizce	Basım Tarihi	01-2019
Kabul Tarihi	–	Yayınlanma Tarihi	01-01-2019
Cilt / Sayı / Sayfa	1176 / 1 / 895–900	DOI	10.1016/j.molstruc.2018.08.090
Makale Linki	https://linkinghub.elsevier.com/retrieve/pii/S0022286018310391
UAK Araştırma Alanları

Özet

A new complex of Cu(II), the composition Cu(C3H7N3O4S)∙H2O, the reaction of thiosemicarbazone glyoxylic acid with copper nitrate in an aqueous medium was synthesised. X-ray diffraction analysis established the composition of the complexes was studied by IR, UV electronic absorption and EPR spectroscopy, and thermogravimetry. Thermogravimetry shows five stages of decomposition in the temperature range 90–990°С. The magnetic susceptibility of the complex is studied. The value of μeff for the complex is 1.76 BM, which is close to the value of one unpaired electron (1.73 BM). The ligand coordinates with the metal atom and consists of monoanionic Cu(C3H7N3O4S)∙H2O polymeric complex connected by Cu–N bonds with neighbouring molecules. The metal centre coordinates with the oxygen of carboxylic, sulfur of thiolic and nitrogen of the azomethine group. The X-ray data and ESR spectra specify a distorted square pyramidal environment around Cu(II) ion.

Anahtar Kelimeler

Crystal structure | Cu-complex | Thiosemicarbazones

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları

Cu(II) complex with thiosemicarbazone of glyoxylic acid as an anion ligand in a polymeric structure

Dergi Adı	JOURNAL OF MOLECULAR STRUCTURE
Kısa Adı	J MOL STRUCT
Yayıncı	ELSEVIER
Açık Erişim	Hayır
ISSN	0022-2860
E-ISSN	1872-8014
Wos Quartile	Q3
Scopus Quartile	Q2
Tarandığı Indeksler	SCIE , Scopus
WoS Kategoriler	CHEMISTRY, PHYSICAL
Scopus Kategoriler	INORGANIC CHEMISTRY \| ANALYTICAL CHEMISTRY \| ORGANIC CHEMISTRY \| SPECTROSCOPY

Cu(II) complex with thiosemicarbazone of glyoxylic acid as an anion ligand in a polymeric structure

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