[Pr2(pdc)3(Hpdc)(H2O)4]n·n(H3hp)·8n(H2O), a One-dimensional coordination polymer containing PrO6N3 tri-capped trigonal prisms and PrO8N mono-capped square anti-prisms (H2pdc = Pyridine 2,6-dicarboxylic Acid, C7H5NO4; 3hp = 3-hydroxy pyridine

Sharif, Shahzad; ŞAHİN, ONUR; Khan, Islam Ullah; Büyükgüngör, Orhan; Harrison, William T.A.

doi:10.3390/cryst2031253

[Pr2(pdc)3(Hpdc)(H2O)4]n·n(H3hp)·8n(H2O), a One-dimensional coordination polymer containing PrO6N3 tri-capped trigonal prisms and PrO8N mono-capped square anti-prisms (H2pdc = Pyridine 2,6-dicarboxylic Acid, C7H5NO4; 3hp = 3-hydroxy pyridine

Yazarlar (5)

Shahzad Sharif
Government College University Lahore, Pakistan

Prof. Dr. Onur ŞAHİN Ondokuz Mayis Üniversitesi, Türkiye

Islam Ullah Khan
Government College University Lahore, Pakistan

Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye

William T.A. Harrison
University Of Aberdeen, İngiltere

Makale Türü	Diğer (Teknik, not, yorum, vaka takdimi, editöre mektup, özet, kitap krıtiği, araştırma notu, bilirkişi raporu ve benzeri) (SCOPUS dergilerinde yayınlanan teknik not, editöre mektup, tartışma, vaka takdimi ve özet türünden makale)
Dergi Adı	Crystals
Dergi ISSN	2073-4352 Dergi Bilgileri (2012)
Makale Dili	İngilizce	Basım Tarihi	08-2012
Kabul Tarihi	–	Yayınlanma Tarihi	27-08-2012
Cilt / Sayı / Sayfa	2 / 3 / 1253–1260	DOI	10.3390/cryst2031253
Makale Linki	https://www.mdpi.com/2073-4352/2/3/1253/pdf?version=1346054420
UAK Araştırma Alanları	Yoğun Madde Fiziği

Özet

The synthesis, structure and some properties of the one-dimensional coordination polymer, [Pr2(pdc)3(Hpdc)]n•n(H3hp)•8n(H2O), (H2pdc = pyridine 2,6-dicarboxylic acid, C7H5NO4; 3hp = 3-hydroxypyridine, C5H5NO) are described. One of the Pr³⁺ ions is coordinated by two O,N,O-tridentate pdc^2-ligands and one tridentate Hpdc^- anion to generate a fairly regular PrO6N3 tri-capped trigonal prism, with the N atoms acting as the caps. The second Pr³⁺ ion is coordinated by one tridentate pdc^2- dianion, four water molecules and two monodentate bridging pdc^2- ligands to result in a PrO8N coordination polyhedron that approximates to a mono-capped square-anti-prism. The ligands bridge the metal-atom nodes into a chain, which extends in the [100] direction. The H3hp⁺ cation and uncoordinated water molecules occupy the inter-chain regions and an N-HLO and numerous O-HLO hydrogen bonds consolidate the structure. The H3hp⁺species appears to intercalate between pendant pdc rings to consolidate the polymeric structure. Crystal data:1 (C33H43N5O29Pr2), Mr = 1255.54, triclinic, P1(No. 2), Z = 2, a = 13.2567(1) Å, b = 13.6304(2) Å, c = 13.6409(2) Å,α = 89.695(1)°, β = 63.049(1)°, γ = 86.105(1)°, V = 2191.16(5) Å³, R(F) = 0.033, wR(F²) = 0.084. © 2011 by the authors; licensee MDPI, Basel, Switzerland.

Anahtar Kelimeler

Intercalation | Nine-coordination | One-dimensional coordination polymer | Praseodymium

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Scopus	3

[Pr2(pdc)3(Hpdc)(H2O)4]n·n(H3hp)·8n(H2O), a One-dimensional coordination polymer containing PrO6N3 tri-capped trigonal prisms and PrO8N mono-capped square anti-prisms (H2pdc = Pyridine 2,6-dicarboxylic Acid, C7H5NO4; 3hp = 3-hydroxy pyridine

Dergi Adı	CRYSTALS
Kısa Adı
Yayıncı	Multidisciplinary Digital Publishing Institute (MDPI)
Açık Erişim	Evet
ISSN	2073-4352
Scopus Quartile	Q3
Tarandığı Indeksler	Scopus
WoS Kategoriler
Scopus Kategoriler	CHEMICAL ENGINEERING (MISCELLANEOUS) \| MATERIALS SCIENCE (MISCELLANEOUS) \| CONDENSED MATTER PHYSICS \| INORGANIC CHEMISTRY

[Pr2(pdc)3(Hpdc)(H2O)4]n·n(H3hp)·8n(H2O), a One-dimensional coordination polymer containing PrO6N3 tri-capped trigonal prisms and PrO8N mono-capped square anti-prisms (H2pdc = Pyridine 2,6-dicarboxylic Acid, C7H5NO4; 3hp = 3-hydroxy pyridine

Paylaş