Synthesis, characterization and spectroscopic studies of novel peripherally tetra-imidazole substituted phthalocyanine and its metal complexes, the computational and …
Yazarlar (4)
Hakkı Türker Akçay
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Selami Karslioğlu
Prof. Dr. Ertan Şahin Sinop Üniversitesi
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Organometallic Chemistry (Q2) | ||
| Makale Dili | – | Basım Tarihi | 08-2012 |
| Cilt / Sayı / Sayfa | 713 / 0 / 1–10 | DOI | – |
| Makale Linki | https://www.sciencedirect.com/science/article/pii/S0022328X12001623 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| Compound (3) was synthesized by the reaction of 4-(4,5-diphenyl-1H-imidazol-2-yl) phenol and 4-nitrophthalonitrile in dry DMF in presence of K2CO3 and obtained as single crystal form suitable for x-ray analysis. Vibrational assignments and electronic transitions of the compound (3) were calculated and compared with the experimental results. Compound (4) was obtained from compound (33), by heating at 160 °C for 24 h under N2 atmosphere in dry N,N dimethyl aminoethanol. Compounds (5–8) were synthesized by the same method applied for the synthesis of compound (4) with addition of the corresponding metal salts (ZnCH3COO2, NiCl2, CoCl2, CuCl2). Prepared phthalocyanines were purified by column chromotography using appropriate solvent system and characterized by elemental analysis 1H NMR, 13C NMR, UV–vis, IR and mass spectra. Aggregation behavior of compound (5) was studied in … |
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