Synthesis, characterization and investigation of electrochemical and spectroelectrochemical properties of peripherally and non-peripherally tetra 2-methyl-5-benzothiazole …
Yazarlar (7)
Ümit Demirbaş
Duygu Akyüz
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Burak Barut
Atıf Koca
Halit Kantekin
İsmail Değirmencioğlu Sinop Üniversitesi
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Synthetic Metals (Q2) | ||
| Makale Dili | – | Basım Tarihi | 09-2017 |
| Cilt / Sayı / Sayfa | 231 / 0 / 112–119 | DOI | – |
| Makale Linki | https://www.sciencedirect.com/science/article/pii/S0379677917301947 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| In this study novel tetra 2-methyl-5-benzothiazole substituted peripherally nickel(II) (6), copper(II) (8), cobalt(II) (10) and non-peripherally nickel(II) (7), copper(II) (9), cobalt(II) (11) phthalocyanines were synthesized. These novel compounds were characterized by a combination of FT-IR, 1H NMR and UV–vis and MALDI-TOF mass spectroscopic techniques. Electrochemical measurements gave well illustrated redox responses for the Pc ring and/or metal center of the complexes. While MPc bearing redox inactive metal centers underwent [MIIPc−2]/[MIIPc−3]1−, [MIIPc−3]1−/[MIIPc−4]2−, [MIIPc−4]2−/[MIIPc−5]3− and [MIIPc−2]1−/[MIIPc−1]1+ redox couples. CoIIPc illustrated [CoIIPc−2]/[CoIPc−2]1−, [CoIPc−2]1−/[CoIPc−3]2−, [CoIPc−3]2−/[CoIPc−4]3− and [CoIIPc−2]/[CoIIPc−2]1+ redox couples respectively during reduction and oxidation processes respectively. Position of the substituents altered the chemical and … |
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