Intermolecular Forces in Porphyrin Crystals
Yazarlar (2)
Jan AK Paul
| Makale Türü | Özgün Makale (Uluslararası alan indekslerindeki dergilerde yayınlanan tam makale) | ||
| Dergi Adı | Inorganic Chemistry | ||
| Dergi ISSN | 0020-1669 | ||
| Makale Dili | – | Basım Tarihi | 01-1995 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-01-1995 |
| Cilt / Sayı / Sayfa | 34 / 1 / 199–201 | DOI | 10.1021/ic00105a033 |
| Makale Linki | https://pubs.acs.org/doi/pdf/10.1021/ic00105a033 | ||
| UAK Araştırma Alanları |
Dedektör Teknolojisi
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| Özet |
| Data on the intermolecular forces in crystals of 2, 4-substituted porphyrin dimethyl esters (DME’s) are reported. Calorimetric measurements show an anomalous behavior at the meltingpoint for two compounds, and vibrational spectroscopy reveals differences in the N—H bonds. Distinctively high Tm values were found for DME’s with formyl at position 2. The experimental data are combined with theoretical evaluations of intermolecular forces in the crystal lattice. These forces are related to the physical and physiological properties of free and protein-bound porphyrins and hemins. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
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| Google Scholar | 3 |