Electrochemical simulation of redox potential development in bioleaching of a pyritic chalcopyrite concentrate
Yazarlar (4)
Mohammad Khoshkhoo
Andrey Shchukarev
Åke Sandström
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Hydrometallurgy (Q1)
Makale Dili – Basım Tarihi 04-2014
Cilt / Sayı / Sayfa 144 / 0 / 7–14 DOI –
Makale Linki https://www.sciencedirect.com/science/article/pii/S0304386X1400022X
UAK Araştırma Alanları
Dedektör Teknolojisi
Özet
The majority of the world's copper reserves are bound in the sulphide mineral chalcopyrite (CuFeS2), but supply of the copper is hindered by the recalcitrance of chalcopyrite to (bio)leaching. The main reason for the slow rate of chalcopyrite dissolution is the formation of a layer on the surface of the mineral that hinders dissolution, termed “passivation”. The nature of this layer and the role of microorganisms in chalcopyrite leaching behaviour are still under debate. Moderately thermophilic bioleaching of a pyritic chalcopyrite concentrate was mimicked in an electrochemical vessel to investigate the effect of the absence and presence of microorganisms in copper dissolution efficiency. Data from the redox potential development during bioleaching was used to program a redox potential controller in an electrochemical vessel to accurately reproduce the same leaching conditions in the absence of microorganisms. Two …
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