New insights into the influence of redox potential on chalcopyrite leaching behaviour
Yazarlar (4)
Mohammad Khoshkhoo
Mark Dopson
Åke Sandström
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Minerals Engineering (Q1)
Makale Dili – Basım Tarihi 01-2017
Cilt / Sayı / Sayfa 100 / 0 / 9–16 DOI –
Makale Linki https://www.sciencedirect.com/science/article/pii/S0892687516303405
UAK Araştırma Alanları
Dedektör Teknolojisi
Özet
Chalcopyrite (CuFeS2) is the most economically important and most refractory copper mineral when treated in conventional sulphate media leaching systems. In this study, the effect of solution redox potential on leaching of a pure and a pyritic chalcopyrite concentrate was investigated using concentrates with fresh and aged surfaces. In experiments using concentrates with fresh surfaces, the response to redox potential depended on the presence of pyrite: fresh pyritic concentrate leached more effectively at low redox potential (in agreement with reductive leaching mechanisms), while the leaching efficiencies from fresh pure concentrate were similar at high and low redox potentials. The data suggested that the reductive leaching mechanism does not necessarily result in higher and faster recoveries in the absence of the galvanic interaction induced by the presence of pyrite. It was also found that exposure of …
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