A novel tetrazole–1, 8-naphthyridine–amide hybrid: first structurally characterized tetrazolo [1, 5-a]-derivative of naphthyridines with a luminescence activity, potency …
Yazarlar (1)
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Makale Dili | – | Basım Tarihi | 02-2025 |
| Cilt / Sayı / Sayfa | 1321 / 0 / 139803–0 | DOI | – |
| Makale Linki | https://www.sciencedirect.com/science/article/pii/S0022286024023123 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| This contribution is devoted to a novel tetrazole–1,8-naphthyridine–amide hybrid N-(tetrazolo[1,5-a][1,8]naphthyridin-8-yl)butyramide (1), which was produced from N-(7‑chloro-1,8-naphthyridin-2-yl)butyramide by reacting with NaN3. In the crystalline state, molecules of 1 exhibited C–H···O intramolecular bonds and produced a 1D chain through N–H···N and C–H···N contacts. Chains produce a supramolecular 2D layer due to π···π interactions. In the UV–vis spectrum, 1 exhibits bands up to ∼360 nm and is emissive with a broad band from about 335 to 450 nm, with the maximum at 365 nm. Fine features of 1 were revealed using the density functional theory (DFT) calculations in water. The computed geometrical parameters are in accordance with the experimental values. The frontier electronic orbitals were found on the molecule except for the propyl fragment, and 1 was determined as a strong electrophile. The … |
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