Synthesis, characterization, crystal structure, electrochemical and photoluminescence properties, DFT and molecular docking studies, and antimicrobial activities of two …
Yazarlar (1)
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Makale Dili | – | Basım Tarihi | 10-2025 |
| Cilt / Sayı / Sayfa | 1342 / 0 / 142763–0 | DOI | – |
| Makale Linki | https://www.sciencedirect.com/science/article/pii/S0022286025014371 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Two octahedral nickel complexes; [Ni(fdtp)2(DMF)2] (1) and [Ni(dcdtp)2(DMF)2] (2), based on 4-((3-fluorophenyl)diazenyl)-3-(trifluoromethyl)-1H-pyrazol-5-ol (fdtp) and 4-((2,4-dichlorophenyl)diazenyl)-3-(trifluoromethyl)-1H-pyrazol-5-ol (dcdtp) were synthesized. The complexes were characterized spectroscopically (FTIR, UV–Vis, Photoluminescence), Mass spectrometry, elemental analyses, electrochemically, thermally, and through Single-crystal X-ray investigations. The formation of the complexes was confirmed by the existence of Ni–O and Ni–N vibrations at bonds were observed as weak bands at 526–497 and 470–438 cm–1. According to the thermogravimetric analyses, the complexes were thermally stable and had relatively high activation energies (585.81 and 730.07 kJ mol–1 for 1, and 2, respectively). Cyclic voltammograms showed that the anodic potential region of 1 and 2 exhibited two irreversible … |
| Anahtar Kelimeler |
