Sulfaguanidine-based schiff bases, synthesis, crystal structure, FT-IR, hirshfeld surface analysis, and concise computational study
Yazarlar (8)
Alqadar Iqbal
University Of Lahore, Pakistan
University Of Lahore, Pakistan
Muhammad Nawaz Tahir
University Of Sargodha, Pakistan
University Of Sargodha, Pakistan
Asghar Ali
University Of Lahore, Pakistan
University Of Lahore, Pakistan
Mehran Feizi-Dehnayebi
Süleyman Demirel Üniversitesi, Türkiye
Süleyman Demirel Üniversitesi, Türkiye
Hazrat Bilal
Sun Yat-Sen University, Çin
Sun Yat-Sen University, Çin
Khurram Shahzad Munawar
University Of Sargodha, Pakistan
University Of Sargodha, Pakistan
Muhammad Ashfaq University Of Sargodha, Pakistan
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Structural Chemistry (Q2) | ||
| Dergi ISSN | 1040-0400 Dergi Bilgileri (2026) | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2026 |
| Cilt / Sayı / Sayfa | 0 / 1 / – | DOI | 10.1007/s11224-026-02735-3 |
| Makale Linki | https://link.springer.com/article/10.1007/s11224-026-02735-3 | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
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| Özet |
| The current work reports the synthesis of three new sulfaguanidine-based Schiff bases: (E)-N-(diaminomethylene)-4-((2-hydroxy-3-methoxybenzylidene)amino)benzenesulfonamide (DHMB), (E)-N-(diaminomethylene)-4-((2,4-dichlorobenzylidene)amino)benzenesulfonamide (DCLB), and (E)-N-(diaminomethylene)-4-((4-fluoro-2-hydroxybenzylidene)amino)benzenesulfonamide (DFHB). The synthesized derivatives were initially characterized by FT-IR spectroscopy to confirm the presence of the azomethine linkage (HC = N), a characteristic aspect of Schiff bases. Then, single-crystal XRD analysis was performed for structural elucidation. The structures of DHMB and DFHB adopt the enol tautomeric form, stabilized by intramolecular O–H⋯N hydrogen bonding, whereas DCLB did not exhibit tautomerism. DFHB exists in a solvated form, while the other structures are non-solvated. Hirshfeld surface analysis reveals … |
| Anahtar Kelimeler |
| DFT | Hirshfeld surface analysis | Molecular docking | Schiff bases | Single crystal | Sulfaguanidine |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 1 |
| Scopus | 1 |
| Google Scholar | 1 |