Complexes formed by a heterocyclic schiff base containing an aminothiophene group with Ni(II) and Co(II) metals and their structural characterization
Yazarlar (5)
Dr. Öğr. Üyesi Şenol Yavuz Hitit University, Türkiye
Prof. Dr. Naki Çolak Hitit University, Türkiye
Öğr. Gör. Tuğrul Yıldırım Hitit University, Türkiye
Prof. Dr. Dursun Ali Köse Hitit University, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2026) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2026 |
| Cilt / Sayı / Sayfa | 1357 / 1 / 145217– | DOI | 10.1016/j.molstruc.2025.145217 |
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| In this study, compound 2, a novel Schiff base ligand containing an aminothiophene group, was synthesized and thoroughly characterized. The amine precursor (1) was condensed with 5-chloro-2-hydroxybenzaldehyde to yield the target ligand in high yield (90%). The ligand's structure was confirmed using FT-IR, 1H-NMR, 13C-APT NMR, LC-MS (-ESI), and elemental analysis.The crystallographic study revealed that the ligand is arranged in the triclinic Pī space group, with two molecules present in each unit cell. The measured C7–N1 and C10–O2 bond lengths exhibit double-bond character, and the phenyl–thiophene dihedral angle of 6.02° points to an almost planar structure. A hydrogen bond formed within the molecule between the phenolic –OH and imine nitrogen, and π···π interactions between adjacent molecules enhanced crystal stability.The ligand reacted with Co2+ and Ni2+ salts under reflux conditions … |
| Anahtar Kelimeler |
| "Aminothiophene" | "Coordination compounds" | "Schiff base" | "Thermal stability" | "X -Ray diffraction analysis" |
Science Direct
Complexes formed by a heterocyclic schiff base containing an aminothiophene group with Ni(II) and Co(II) metals and their structural characterization
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| Atıf Sayıları | |
| Web of Science | 1 |
| Google Scholar | 1 |