Novel heteroleptic metal cation complexes of anisic acid/N, N-diethylnicotinamide ligands and biological applications
Yazarlar (4)
Esra Çataldağ
Hitit University, Türkiye
Prof. Dr. Dursun Ali Köse Hitit University, Türkiye
Arş. Gör. Gizem Özlük Hitit University, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q2)
Dergi ISSN 0022-2860 Dergi Bilgileri (2026)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2026
Cilt / Sayı / Sayfa 1357 / 1 / 145219– DOI 10.1016/j.molstruc.2025.145219
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
Five different heteroleptic complex structures were synthesized by the coordination of anionic p-methoxybenzoate (anisate) and neutral N,N-diethylnicotinamide (niketamide) ligands to transition metal cations (Mn2+, Co2+, Ni2+, Cu2+ and Zn2+). The similarity of the spectroscopic and thermal properties of the Ni2+ cation-centered complex, whose single crystal structure was solved, to other complexes supports the suggestion that the structures are isostructural. Chemical composition analysis and other spectroscopic analysis results support the idea that the Cu2+ cation-centered structure, unlike the others, is in five-fold coordination. It is predicted that the six-fold coordination complexes (Mn2+, Co2+, Ni2+ and Zn2+) are coordinated by two anisate anions, two neutral nicotinamide ligands, and two crystal waters, while the Cu2+ structure is coordinated with a single crystal water content. It was also determined that …
Anahtar Kelimeler
"P-methoxybenzoate" | "Anisate" | "N-diethylnicotinamide" | "Heteroleptic complexes" | "Biological activity" | "Structural analysis"