Well-defined palladium N heterocyclic carbene complexes bearing CF3 moiety: Synthesis, characterization, crystal structure, direct C4-arylation of 3,5-dimethylisoxazole and antioxidant activity
Yazarlar (5)
Ayşegül Kalçık
Dr. Öğr. Üyesi Nazan Kaloğlu Türkiye
Prof. Dr. Serhat Keser Türkiye
Prof. Dr. Zarife Sibel ŞAHİN Sinop Üniversitesi, Türkiye
Serpil Demir Düşünceli Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | JOURNAL OF ORGANOMETALLIC CHEMISTRY (Q2) | ||
| Dergi ISSN | 0022-328X Dergi Bilgileri (2026) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 02-2026 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-02-2026 |
| Cilt / Sayı / Sayfa | 1045 / 0 / – | DOI | 10.1016/j.jorganchem.2025.123975 |
| Makale Linki | https://doi.org/10.1016/j.jorganchem.2025.123975 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| A series of palladium N-heterocyclic carbene (NHC) complexes including trans-[Pd(NHC)Br2L] (L = C5H5N, 3-ClC5H4N, and N-methylimidazole) and [Pd(NHC)2Br2] have been prepared from {1-(benzyl)-3- (3,5-(bis(trifluoromethyl)benzyl)benzimidazolium bromide}. The structures of these new compounds were confirmed by NMR, FT-IR, and elemental analyses. The crystal structures of the dibromo- [1-(benzyl)-3- (3,5-(bis(trifluoromethyl)benzyl)benzimidazole-2-ylidene]-(pyridine)-palladium(II) and dibromo- [1-(benzyl)-3- (3,5-(bis(trifluoromethyl)benzyl)benzimidazole-2-ylidene]-(N-methylimidazole)-palladium(II) were determined by single-crystal X-ray diffraction. Palladium complexes were developed as efficient pre-catalysts for direct C4-arylation of 3,5-dimethylisoxazole and aryl bromides. Biological efficiency of trans-[Pd(NHC)Br2L]was evaluated by antioxidant activities like ABTS, OH and DPPH radical … |
| Anahtar Kelimeler |
| Palladium complex | N -Heterocyclic carbene | Direct C4-arylation | Isoxazole | Antioxidant activity |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 4 |
| Google Scholar | 5 |