COPPER(II) COMPLEX WITH PYRAZINE-AND TRIAZINE-MODULATED TRIPYRIDYLDIAMINE LIGAND: SYNTHESIS, CRYSTAL STRUCTURE, MAGNETIC, AND ANTIMICROBIAL PROPERTIES
Yazarlar (13)
S. Z. Ismayilova
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
M. H. Osmanli Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
R. H. Ismayilov Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
D. B. Tagiyev
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
M. T. Huseynova Ministry of Science And Education of The Republic of Azerbaijan, Azerbaycan
K. R. Gahramanova
Ministry of Science And Education of The Republic of Azerbaijan, Azerbaycan
Ministry of Science And Education of The Republic of Azerbaijan, Azerbaycan
A. A. Medjidov
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
B. Yalcin
Marmara Üniversitesi, Türkiye
Marmara Üniversitesi, Türkiye
F. F. Valiyev
State Oil Company of The Azerbaijan Republic, Azerbaycan
State Oil Company of The Azerbaijan Republic, Azerbaycan
M. A. Bayramov
Institute of Physics Public Legal Entity, Azerbaycan
Institute of Physics Public Legal Entity, Azerbaycan
L. Sh Guliyeva Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
S. M. Peng
National Taiwan University, Tayvan
National Taiwan University, Tayvan
| Makale Türü |
Özgün Makale
(SCOPUS dergilerinde yayınlanan tam makale)
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| Dergi Adı | Azerbaijan Chemical Journal | ||
| Dergi ISSN | 0005-2531 Dergi Bilgileri (2025) | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2025 |
| Cilt / Sayı / Sayfa | 2025 / 4 / 23–33 | DOI | – |
| Makale Linki | https://cyberleninka.ru/article/n/copper-ii-complex-with-pyrazineand-triazine-modulated-tripyridyldiamine-ligand-synthesis-crystal-structure-magnetic-and | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
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| Özet |
| Using the pyrazineand triazine-modulated tripyridyldiamine ligand 6-phenyl-N2,N4-di(pyrazin-2-il)-1,3,5-triazine-2,4-diamine (H2dpztzda), a new mononuclear copper(II) complex [Cu(H2dpztzda)(NO3)2]∙2C3H7NO 1 has been synthesized, structurally characterized, and its antimicrobial properties studied. According to the single crystal X-ray analysis of complex 1, Cu(II) exhibits five coordination with a distorted trigonal bipyramidal geometry. The "inverted type" of EPR spectra (g┴ > g||~ ge), alongside results from magnetic moment susceptibility and electronic spectrum studies, collectively support this observation. The calculated Addison value for 1 is τ5 = 0.54, indicating also that the Cu(II) center possesses distorted trigonal bipyramidal geometry. The H2dpztzda molecule coordinates with the Cu(II) as a tridentate ligand. Complex 1 exhibits two types of hydrogen bonding: classical and non-classical. It has been shown that the interactions involving C-H‧‧‧π, π-π, and hydrogen bonding significantly influence the crystal packing of synthesised complex 1 and play a crucial role in the formation of supramolecular motifs. The antimicrobial activity of the compounds was evaluated using the traditional well diffusion method. Both compounds (complex 1 and H2dpztzda ligand) analyzed for antimicrobial activity showed highly effective results against the bacteria Pseudomonas aeruginosa, Mycobacterium phlei, and the fungi Aspergillus niger and Penicillium chrysogenum in lubricants and coolants. |
| Anahtar Kelimeler |
| Antimicrobial agents | Copper complex | Crystal structure | Hydrogen bonds | Modulated oligo-α-aminopyridine ligand | Spectroscopy |