Synthesis, structural exploration, Hirshfeld surface analysis and computational study of two novel organosulfur compounds derived from mercaptoacetic acid
Yazarlar (8)
Sabiya Osmanova
Academician A.M. Guliyev Institute Of Chemistry Of Additives Ministry Of Science And Education Repub, Azerbaycan
Academician A.M. Guliyev Institute Of Chemistry Of Additives Ministry Of Science And Education Repub, Azerbaycan
Muhammad Ashfaq University Of Sargodha, Pakistan
Rebaz Obaid Kareem
University Of Halabja, Irak
University Of Halabja, Irak
Muhammad Nawaz Tahir
University Of Sargodha, Pakistan
University Of Sargodha, Pakistan
Yousif Hussein Azeez
University Of Halabja, Irak
University Of Halabja, Irak
Rebaz Anwar Omer
Koya University, Irak
Koya University, Irak
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Malahat Kurbanova
Baku State University, Azerbaycan
Baku State University, Azerbaycan
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2026) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2026 |
| Cilt / Sayı / Sayfa | 1353 / 1 / 144775– | DOI | 10.1016/j.molstruc.2025.144775 |
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The reaction of 2-aminopyridine with mercaptoacetic acid was carried out in a benzene solution at a molar ratio of the initial components of 1: 1. The thiylated reaction of p-bromoacetophenone with mercaptoacetic acid was carried out in a benzene solution, with a molar ratio of the initial components of 1: 4. As a result, new compounds were obtained: 2-aminopyridin-1-ium-2, 2′-disulfanediyldiacetate (ASA) and 1, 1-bis-(carboxymethylthio)-1-p-bromophenylethane (BSA). The structure of the newly synthesized compounds was confirmed by using single crystal XRD technique. The structure of ASA is a salt in which there exist two cations and one dianion in the asymmetric unit. The cations and dianions are interlinked by NH⋯ O and CH⋯ O bonding and further stabilization of the crystal packing is due to weak π⋯ π and CO⋯ π interactions. In second compound BSA, molecules are interlinked in the form of dimers … |
| Anahtar Kelimeler |
| "Mercaptoacetic acid" | "P-bromoacetophenone" | "2-aminopyridine" | "Crystal structure" | "Hirshfeld surface analysis" | "DFT" |
Science Direct
Synthesis, structural exploration, Hirshfeld surface analysis and computational study of two novel organosulfur compounds derived from mercaptoacetic acid
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 5 |
| Scopus | 5 |
| Google Scholar | 5 |