The determination of photophysical and photochemical parameters of novel metal-free,zinc(II) and lead(II) phthalocyanines bearing 1,2,4-triazole groups
Yazarlar (5)
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Prof. Dr. Ümit Demirbaş Karadeniz Technical University, Türkiye
Prof. Dr. Mehmet Pişkin Çanakkale Onsekiz Mart Üniversitesi, Türkiye
Mahmut Durmuş Gebze Teknik Üniversitesi, Türkiye
Prof. Dr. Halit Kantekin Karadeniz Teknik Üniversitesi, Türkiye
Bildiri Türü Tebliğ/Bildiri Bildiri Dili İngilizce
Bildiri Alt Türü
Bildiri Niteliği Web of Science Kapsamındaki Kongre/Sempozyum
DOI Numarası 10.1016/j.synthmet.2016.05.008
Kongre Adı 3. Uluslarası İlaç ve Eczacılık Konbgresi
Kongre Tarihi 26-04-2017 / 29-04-2017
Basıldığı Ülke Basıldığı Şehir
Bildiri Linki https://linkinghub.elsevier.com/retrieve/pii/S0379677916301485
UAK Araştırma Alanları
Anorganik Kimya
Özet
In this study the synthesis and characterization of novel phthalonitrile compound (3) and its metal-free (4), zinc(II) (5), and lead(II) (6) phthalocyanines bearing four 4-(4-methoxyphenylethyl)-5-propyl-2,4-dihydro-3H-1,2,4-triazol-3-one groups at peripheral positions were synthesized for the first time. These novel compounds were fully characterized by FT-FT-IR, 1H NMR, UV–vis and MALDI-TOF mass spectroscopic techniques. Their photochemical and photophysical properties were also investigated in N,N-dimethylformamide solutions. In addition, the effect of 4-(4-methoxyphenylethyl)-5-propyl-2,4-dihydro-3H-1,2,4-triazol-3-one groups as substituents and central metal ions (without metal, zinc(II) or lead(II)) in the phthalocyanine cavity on these properties were also compared. The studied zinc(II) or lead(II) phthalocyanines can be potential Type II photosensitizers for photodynamic therapy in cancer applications …
Anahtar Kelimeler
Lead | Metal-free | Photochemical | Photophysical | Phthalocyanine | Zinc