Synthesis of silver/epoxy nanocomposites by visible light sensitization using highly conjugated thiophene derivatives
Yazarlar (6)
Öğr. Gör. Yusuf Yagci İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Turan Ozturk İstanbul Teknik Üniversitesi, Türkiye
Sophie Marchi Politecnico Di Torino, İtalya
Sabrina Grassini
Politecnico Di Torino, İtalya
Marco Sangermano
Politecnico Di Torino, İtalya
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Reactive and Functional Polymers (Q1)
Dergi ISSN 1381-5148 Dergi Bilgileri (2011)
Makale Dili İngilizce Basım Tarihi 08-2011
Cilt / Sayı / Sayfa 71 / 8 / 857–862 DOI 10.1016/j.reactfunctpolym.2011.05.012
Makale Linki http://www.scopus.com/inward/record.url?eid=2-s2.0-79958024916&partnerID=MN8TOARS
UAK Araştırma Alanları
Fen Bilimleri ve Matematik
Özet
A novel one-pot photochemical strategy for the preparation of silver-epoxy nanocomposite using a highly conjugated thiophene derivative and silver salt was described. Electron transfer reaction between photoexcited 3,5-bis(4- methoxyphenyl)dithieno[3,2-b;2,3-d]thiophene), (P-DDT) and silver salt could be achieved under visible light irradiation. The polymerization process has been demonstrated to be highly efficient in the concomitant cationic ring-opening polymerization of epoxy ring and silver ion reduction. The produced nanocomposite contains spherical shaped nanoparticles homogenously dispersed in the epoxy network with narrow size distribution in between 25 and 50 nm. © 2011 Elsevier Ltd. All rights reserved.
Anahtar Kelimeler
Cationic ring-opening polymerization | Epoxy matrix | Silver-epoxy nanocomposites