Synthesis and spectroscopic characterization of new double-armed benzo-15-crown-5 derivatives and their sodium complexes
Yazarlar (2)
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Zeliha Hayvalbox
Ankara Üniversitesi, Türkiye
Ankara Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Heteroatom Chemistry (Q3) | ||
| Dergi ISSN | 1042-7163 Dergi Bilgileri (2013) | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2013 |
| Cilt / Sayı / Sayfa | 24 / 2 / 100–109 | DOI | 10.1002/hc.21070 |
| Makale Linki | https://onlinelibrary.wiley.com/doi/abs/10.1002/hc.21070 | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
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| Özet |
| Double‐armed crown ether aldehydes (1–3) were synthesized from the reaction of 2 equiv salicylaldehyde, 4‐hydroxy‐3‐methoxybenzaldehyde (vanillin), and 3‐hydroxy‐4‐methoxybenzaldehyde (iso‐vanillin) with 4′,5′‐bis(bromomethyl)benzo‐15‐crown‐5. New crown ethers imine compounds (4–9) were synthesized by the condensation of corresponding crown ether aldehydes (1–3) with 4‐amino‐1,2‐dihydro‐1,5‐dimethyl‐2‐phenyl‐3H‐pyrazole‐3‐one and 2‐furan‐2‐yl‐methylamine. Sodium complexes (1a–9a) of the crown compounds form crystalline 1:1 (Na+:ligand) stoichiometries and were also synthesized. The structures of the crown ether aldehydes (1–3), imine compounds (4–9), and complexes (1a–9a) were confirmed on the basis of elemental analyses, IR, 1H and 13C NMR, and mass spectrometry. © 2013 Wiley Periodicals, Inc. Heteroatom Chem 24:100–109, 2013; View this article online at … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 4 |
| Google Scholar | 9 |