Functionalization of fullerene (C60) with metformine to immobilized palladium as a novel heterogeneous and reusable nanocatalyst in the Suzuki-Miyaura coupling reaction at room temperature

Veisi, Hojat; Masti, Ramin; Kordestani, Davood; Safaei, Maryam; ŞAHİN, ONUR

doi:10.1016/j.molcata.2014.01.007

Functionalization of fullerene (C60) with metformine to immobilized palladium as a novel heterogeneous and reusable nanocatalyst in the Suzuki-Miyaura coupling reaction at room temperature

Yazarlar (5)

Hojat Veisi
Payame Noor University

Ramin Masti
Payame Noor University

Davood Kordestani
Payame Noor University

Maryam Safaei
Payame Noor University

Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Journal of Molecular Catalysis A Chemical (Q2)
Dergi ISSN	1381-1169 Dergi Bilgileri (2014)
Makale Dili	İngilizce	Basım Tarihi	04-2014
Cilt / Sayı / Sayfa	385 / 1 / 61–67	DOI	10.1016/j.molcata.2014.01.007
Makale Linki	http://www.scopus.com/inward/record.url?eid=2-s2.0-84894033970&partnerID=MN8TOARS
UAK Araştırma Alanları	Fen Bilimleri ve Matematik

Özet

Pd supported on biguanide(metformine)-functionalized fullerene (C 60-Met/Pd²⁺) hybrid materials was fabricated for the first time. The catalyst prepared was characterized by X-ray diffraction spectroscopy (XRD), Fourier transform infrared (FT-IR), thermogravimetric analysis (TGA), and transmission electron microscopy (TEM). The catalyst showed excellent activity Suzuki-Miyaura coupling reaction of different aryl iodides and bromides with phenylboronic acid at room temperature in the EtOH:H2O (1:1) mixture as solvent. The yields of the products were in the range from 85% to 98%. The catalyst can be readily recovered and reused at least 6 consecutive cycles without significant loss in its catalytic activity. This is the new example for the development of fullerene (C60-Met-Pd) complexes which can be used as efficient recyclable catalysts without palladium leaching. © 2014 Elsevier B.V.

Anahtar Kelimeler

Biguanide-functionalized C60 | Metformine | Pd catalyst | Suzuki-Miyaura coupling

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Scopus	77

Functionalization of fullerene (C60) with metformine to immobilized palladium as a novel heterogeneous and reusable nanocatalyst in the Suzuki-Miyaura coupling reaction at room temperature

Dergi Adı	JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Kısa Adı	J MOL CATAL A-CHEM
Yayıncı	ELSEVIER SCIENCE BV
Açık Erişim	Hayır
ISSN	1381-1169
E-ISSN	1873-314X
Wos Quartile	Q2
Tarandığı Indeksler	SCIE
WoS Kategoriler	CHEMISTRY, PHYSICAL
Scopus Kategoriler

Functionalization of fullerene (C60) with metformine to immobilized palladium as a novel heterogeneous and reusable nanocatalyst in the Suzuki-Miyaura coupling reaction at room temperature

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