Synthesis, Characterization and Antimicrobial Activity of Schiff Bases Including Three Hydroxy Groups and Their CoCl2, PdCl2, CuCl2 and ZnCl2 Complexes
Yazarlar (7)
Elham Alterhoni
Istanbul University-Cerrahpasa, Türkiye
Istanbul University-Cerrahpasa, Türkiye
Prof. Dr. Aydin Tavman Istanbul University-Cerrahpasa, Türkiye
Doç. Dr. Demet Gürbüz Istanbul University-Cerrahpasa, Türkiye
Doç. Dr. Mayram Hacioglu Istanbul Üniversitesi, Türkiye
Dr. Öğr. Üyesi Adem Çinarli Istanbul University-Cerrahpasa, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
A. Seher Birteksöz Tan
Istanbul Üniversitesi, Türkiye
Istanbul Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Chemistryselect (Q3) | ||
| Dergi ISSN | 2365-6549 Dergi Bilgileri (2020) | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2020 |
| Cilt / Sayı / Sayfa | 5 / 31 / 9730–9735 | DOI | 10.1002/slct.202001498 |
| Makale Linki | https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/slct.202001498 | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
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| Özet |
| Four Schiff bases, (3/4/2/4)‐{[(2‐hydroxy‐5‐methylphenyl)imino]methyl}benzene‐1,2/1,3/1,4/1,2‐diols (H3L1‐H3L4), derived from 2,3/2,4/2,5/3,4‐dihydroxybenzaldehydes and 2‐amino‐4‐methylphenol, and their CoCl2, PdCl2, CuCl2 and ZnCl2 complexes were synthesized and characterized. The structures of the complexes were suggested on the basis of elemental analysis, TGA, molar conductivity, magnetic moment, FT‐IR, UV‐vis and NMR spectroscopy. According to the analytical and spectral data, the ligands H3L1, H3L2 and H3L3 acted as tridentate, giving chelate structures in the complexes, via the C=N nitrogen and two phenolate oxygen atoms whereas H3L4 acted as bidentate. In addition, the crystal structure of H3L1 was determined by X‐ray diffraction. The spectral data show that there is keto‐enol tautomerization in the ligands and keto form is dominant in H3L1 and H3L3 while enol form is in H3L2 … |
| Anahtar Kelimeler |
| 4-Methylphenol | Antimicrobial | Chelates | Dihydroxy | Schiff bases |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 8 |
| Scopus | 6 |
| Google Scholar | 8 |