Unprecedented Formation of Potassium Borate Based Carbonate from Chloral Hydrate, Potassium Carbonate and Boric Acid
Yazarlar (1)
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | X Ray Structure Analysis Online | ||
| Dergi ISSN | 1883-3578 Dergi Bilgileri (2021) | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2021 |
| Cilt / Sayı / Sayfa | 37 / 1 / 45–47 | DOI | 10.2116/xraystruct.37.45 |
| Makale Linki | https://www.jstage.jst.go.jp/article/xraystruct/37/0/37_45/_article/-char/ja/ | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
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| Özet |
| The structure of the reaction product of boric acid, chloral hydrate, and potassium carbonate in H2O, potassium bis (carbonato) borate hydrate K [B (CO2-μ-O-CO2) 2]· 2H2O, was determined by X-ray crystallography. The compound crystallized in the orthorhombic system, and was characterized to be in the space group Aba2, with cell parameters of a= 11.0579 (10) Å, b= 11.1695 (10) Å, c= 9.0504 (9) Å, Z= 4, and V= 1117.83 (18) Å3. In the crystal structure, intermolecular O–H··· O hydrogen bonds link the molecules into a supramolecular structure, in which they may be effective in stabilizing the structure. The B atom espouses a distorted tetrahedral geometry with four O atoms of carbonate ligands. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 1 |
| Google Scholar | 2 |