COPPER(II) COMPLEX OF THE PYRAZINE-MODULATED OLIGO-α-AMINOPYRIDINE AS A COORDINATION POLYMERS’ PROMISING BUILDING BLOCK
Yazarlar (10)
S. Z. Ismayilova
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
R. H. Ismayilov Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
D. B. Tagiyev
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
B. Yalcin
Marmara Üniversitesi, Türkiye
Marmara Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
A. A. Medjidov
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
M. T. Huseynova
Academician A.M. Guliyev Institute of Chemistry of Additives Ministry of Science And Education Repub, Azerbaycan
Academician A.M. Guliyev Institute of Chemistry of Additives Ministry of Science And Education Repub, Azerbaycan
L. S. Guliyeva
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
Institute of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry of Science, Azerbaycan
R. J. Gasimov
Institute of Physics Public Legal Entity, Azerbaycan
Institute of Physics Public Legal Entity, Azerbaycan
S. M. Peng
National Taiwan University, Tayvan
National Taiwan University, Tayvan
| Makale Türü |
Özgün Makale
(SCOPUS dergilerinde yayınlanan tam makale)
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| Dergi Adı | Chemical Problems | ||
| Dergi ISSN | 2221-8688 Dergi Bilgileri (2025) | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2025 |
| Cilt / Sayı / Sayfa | 4 / 23 / 476–482 | DOI | – |
| Makale Linki | https://cyberleninka.ru/article/n/copper-ii-complex-of-the-pyrazine-modulated-oligo-aminopyridine-as-a-coordination-polymers-promising-building-block | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
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| Özet |
| Through the pyrazine-modulated tetrapyridyltriamine ligand N2-(pyrazin-2-yl)-N6-(6-(pyrazin-2-ylamino)pyridin-2-yl)pyridine-2,6-diamine (H3pzpz) (1), a new mononuclear copper(II) complex [Cu(H3pzpz)(NO3)]∙NO3∙3H2O (2) has been synthesized and structurally characterized. The copper(II) atom in complex 2 exhibits a distorted square pyramidal geometry with an Addison parameter value of 0.39 (σ = 0.39). In compound (2), H3pzpz (1) acts as a tetradentate N4-donor ligand and coordinates to the Cu(1) ion in an anti-anti-anti-anti conformation. The single crystal X-ray analysis revealed a distorted square pyramidal geometry of the complex (2), which is consistent with the parameters of EPR spectra, measured magnetic moment susceptibility, and electronic spectrum studies. Observed extensive intermolecular hydrogen bond interactions (classical and non-classical) play an important role in the formation of the 3D supramolecular network and crystal packing of this complex. The complex (2) has been identified as a promising building block for the construction of coordination polymers. |
| Anahtar Kelimeler |
| Copper complex | Crystal structure | Hydrogen bonds | Modulated oligo-α-aminopyridine ligand | Supramolecular networks |
