SYNTHESİS, PHOTOPHYSİCAL AND PHOTOCHEMİCAL PROPERTİES OF NOVEL TETRA SUBSTİTUTED METAL FREE AND METALLOPHTHALOCYANİNES BEARİNG TRİAZİNE UNİTS
Yazarlar (6)
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Prof. Dr. Ümit Demirbaş Karadeniz Technical University, Türkiye
Prof. Dr. Hakkı Türker Akçay Recep Tayyip Erdoğan Üniversitesi, Türkiye
Prof. Dr. Mehmet Pişkin Çanakkale Onsekiz Mart Üniversitesi, Türkiye
Mahmut Durmuş Gebze Teknik Üniversitesi, Türkiye
Prof. Dr. Halit Kantekin Karadeniz Teknik Üniversitesi, Türkiye
Bildiri Türü Tebliğ/Bildiri Bildiri Dili İngilizce
Bildiri Alt Türü
Bildiri Niteliği Web of Science Kapsamındaki Kongre/Sempozyum
DOI Numarası 10.1016/j.jorganchem.2012.11.001
Kongre Adı 3. Uluslararası İlaç ve Eczacılık Kongresi
Kongre Tarihi 26-04-2017 / 29-04-2017
Basıldığı Ülke Türkiye Basıldığı Şehir
Bildiri Linki https://linkinghub.elsevier.com/retrieve/pii/S0022328X12006493
UAK Araştırma Alanları
Anorganik Kimya
Özet
The synthesis and characterization of peripherally tetra 2-(4,6-diphenyl-1,3,5-triazine-2-yl)-5-(hexyloxy)phenoxy substituted metal-free (4), zinc(II) (5), oxotitanium(IV) (6), lead(II) (7), nickel(II) (8), copper(II) (9) and cobalt(II) (10) were described for the first time in this study. The photophysical and photochemical properties of metal-free (4), zinc(II) (5), oxotitanium(IV) (6) and lead(II) (7) phthalocyanines were investigated in toluene. The synthesized nickel(II) (8), copper(II) (9) and cobalt(II) (10) phthalocyanines were not evaluated for this purpose because of paramagnetic behavior of the central transition metals in the cavity for these complexes. General trends were described for photodegradation, singlet oxygen and fluorescence quantum yields, and fluorescence lifetimes of these compounds in toluene. The influence of the variety of central metal ions in phthalocyanine cavity on the spectroscopic, photophysical and …
Anahtar Kelimeler
Photochemical | Photophysical | Phthalocyanine | Singlet oxygen | Triazine