Diphenic acid/nicotinamide complexes of CoII, CuII and ZnII. Synthesis and structural investigation
Yazarlar (4)
Prof. Dr. Zarife Sibel ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Arş. Gör. Özge Dağlı Hitit Üniversitesi, Türkiye
Prof. Dr. Dursun Ali Köse Hitit Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q2) | ||
| Dergi Tarandığı Indeksler | |||
| Makale Dili | İngilizce | Basım Tarihi | 10-2016 |
| Cilt / Sayı / Sayfa | 117 / 0 / 214–223 | DOI | – |
| Makale Linki | https://www.sciencedirect.com/science/article/pii/S0277538716302042 | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
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| Özet |
| The complexes of diphenic acid with Co II and Cu II metals and diphenic acid/nicotinamide mixed ligand with Co II and Zn II metals were synthesized and characterized of structural properties by elemental analysis, FT-IR spectra, thermo analytic TG-DTG/DTA and crystal X-ray diffraction methods. The pure ligand complexes of diphenic acid (C 14 H 16 O 8 Co (1), C 14 H 16 O 8 Cu (2)) and mixed ligand complexes of diphenic acid/nicotinamide (C 40 H 38 N 4 O 14 Co (3), C 40 H 38 N 4 O 14 Zn (4)) are similar to each other and they have P2 1, P2 1/n and P 1¯ space groups. The diphenic acid ligands in 1 and 2 complexes were coordinated to metal cations as dianionic bridge and in the others complexes (3 and 4) it was involved as monoanionic counter ion. The complexes of 1 and 2 are linked into sheets by a combination of O–H⋯ O hydrogen bonds and the others complexes of 3 and 4 are linked into sheets by a … |
| Anahtar Kelimeler |
