| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Thermal Analysis and Calorimetry (Q2) | ||
| Dergi Tarandığı Indeksler | |||
| Makale Dili | İngilizce | Basım Tarihi | 05-2019 |
| Cilt / Sayı / Sayfa | 136 / 4 / 1467–1480 | DOI | – |
| Makale Linki | https://search.ebscohost.com/login.aspx?direct=true&profile=ehost&scope=site&authtype=crawler&jrnl=13886150&AN=135841882&h=%2BfZ1uma1hOOtZVceOMMRa9M6B61a%2F2smaAzULD3C6Z9tagqlmOwTD7OQZaE1XaLfPpyZYxFkCWSom%2BUdRSzhOQ%3D%3D&crl=c | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
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| Özet |
| Abstract The coumarilate (coum−) and 1, 10-phenanthroline (phen) mixed ligand complexes of Co (II)(1), Ni (II)(2) Cu (II)(3) and Zn (II)(4) were synthesized and structural characterizations were performed by using elemental analysis, magnetic susceptibility, solid-state UV–Vis, FTIR spectra, thermoanalytical TG-DTG/DTA and single-crystal X-ray diffraction methods. The Co (II) and Ni (II) complexes are salt-type compounds, and they have two moles phen ligands bound as bidentate, two moles aqua ligands in coordination sphere and two moles anionic coum− ligand outside of the coordination unit as the counter-ion of the molecular structure. At the same time, the Co (II) and Ni (II) complexes have five moles of aqua ligands as hydrated water outside of the molecules. It was obtained that Cu (II) and Zn (II) complex structures contain one mole of phen ligand, two moles coordinated (coum−) ligand and a one-mole … |
| Anahtar Kelimeler |