Novel potassium-boron metal-organic frameworks: Influence of ligand variation on structural and hydrogen storage properties
Yazarlar (4)
Doç. Dr. Demet Özer Hacettepe Üniversitesi, Türkiye
Prof. Dr. Dursun Ali Köse Hitit University, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Nurşen Altuntaş Öztaş Hacettepe Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2025) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2025 |
| Cilt / Sayı / Sayfa | 1339 / 1 / 142379–0 | DOI | 10.1016/j.molstruc.2025.142379 |
| Makale Linki | https://doi.org/10.1016/j.molstruc.2025.142379 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| In this study, two novel potassium-based metal-organic frameworks (MOFs) mediated by boric acid were synthesized via a one-pot self-assembly reaction using terephthalic acid and acetylenedicarboxylic acid as ligands in ethyl acetate. The synthesized compounds were thoroughly characterized using Fourier-transform infrared spectroscopy (FT-IR), powder X-ray diffraction (p-XRD), thermogravimetric analysis (TGA), elemental analysis, and single-crystal X-ray diffraction (sc-XRD). Structural analysis revealed the molecular formulas of the new compounds as C16H18B2K4O16 and C2H3BKO5, respectively. Both compounds exhibited high thermal stability. The Brunauer–Emmett–Teller (BET) surface area measurements indicated values of 2.152 m²/g for the potassium terephthalate-boron complex and 4.468 m²/g for the potassium acetylenedicarboxylate-boron complex. Variations in the ligands influenced the … |
| Anahtar Kelimeler |
| Acetylene dicarboxylic acid | B-MOF | Potassium | Terephthalic acid |
Science Direct
Novel potassium-boron metal-organic frameworks: Influence of ligand variation on structural and hydrogen storage properties
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 1 |
| Scopus | 1 |
| Google Scholar | 1 |