ONN donor half-salen ligands and their dioxomolybdenum(VI) complexes: Synthesis, crystal structure, experimental-theoretical characterizations and molecular docking studies
Yazarlar (6)
Eylem Dilmen Portakal
Istanbul University-Cerrahpasa, Türkiye
Istanbul University-Cerrahpasa, Türkiye
Prof. Dr. Savaş Kaya Cumhuriyet Üniversitesi, Türkiye
Avni Berisha Universiteti İ Prishtinës, Sırbistan
Dr. Öğr. Üyesi Yeliz Kaya Istanbul University-Cerrahpasa, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Ayşe Erçağ Istanbul University-Cerrahpasa, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2025) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2025 |
| Cilt / Sayı / Sayfa | 1330 / 1 / 141508–0 | DOI | 10.1016/j.molstruc.2025.141508 |
| Makale Linki | https://doi.org/10.1016/j.molstruc.2025.141508 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The half-salen ligand (L1) synthesized from 3,4-diaminobenzophenone with 2‑hydroxy-1-naphthaldehyde and the new half-salen ligand (L2) synthesized from 4-(diethylamino)salicylaldehyde were used in the preparation of dioxomolybdenum(VI) complexes (C1 and C2). The characterization of the synthesized compounds was carried out by elemental analysis, IR, 1H NMR, UV–Vis and conductivity measurements. The molecular structure of the C2 complex was elucidated by X-ray crystallography. Spectroscopic data show that the half-salen ligands behave as dibasic tridentate ligands and coordinate via phenolic oxygen, azomethine nitrogen and primary amine nitrogen. Both the primary amine group and the hydroxyl group bonded to the molybdenyl center by losing one proton. The complexes, [MoO 2 (L1-L2)(Solv)], are nonelectrolyte and octahedral in structure. The sixth coordination is completed by a solvent … |
| Anahtar Kelimeler |
| 3,4-diaminobenzophenone | Crystal structure | Dioxomolybdenum(VI) complexes | ONN ligands | theoretical calculations |
Science Direct
ONN donor half-salen ligands and their dioxomolybdenum(VI) complexes: Synthesis, crystal structure, experimental-theoretical characterizations and molecular docking studies
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 3 |
| Scopus | 3 |
| Google Scholar | 4 |