Pyridine-2,6-Dicarboxylic Acid As a Facile and Highly Selective “Turn-Off” Fluorimetric Chemosensor for Detection of Cu (II) Ions in Aqueous Media
 
Yazarlar (9)
Javed Hussain Shah
Government College University Lahore, Pakistan
Shahzad Sharif
Government College University Lahore, Pakistan
Muhammad Shahbaz
Government College University Lahore, Pakistan
Bilal Riaz
Government College University Lahore, Pakistan
Sundas Shahzad
Government College University Lahore, Pakistan
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Khurram Shahzad Munawar University Of Mianwali, Pakistan
Hijaz Ahmad Università Telematica Internazionale Unınettuno, İtalya
Essam A. Al‑Ammar
King Saud University, Suudi Arabistan
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Fluorescence (Q2)
Dergi ISSN 1053-0509 Dergi Bilgileri (2025)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 05-2025
Kabul Tarihi 05-05-2024 Yayınlanma Tarihi 28-05-2024
Cilt / Sayı / Sayfa 35 / 5 / 3439–3448 DOI 10.1007/s10895-024-03764-z
Makale Linki https://doi.org/10.1007/s10895-024-03764-z
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
Copper metal is third most abundant trace element in human body. Determination of Cu (II) ions is a burning topic in field of environment protection and food safety because of its significant impact on ecosystem. In this study, 2,6-pyridine dicarboxylic acid (PDA) has been explored as “turn-off” florescent probe for florescent detection of Cu (II) ions. This sensor showed highly selective complexing ability towards Cu (II) ions. Addition of aqueous solution of Cu (II) ions remarkably quenched the fluorescence intensity of PDA while, on contrary, there was no any prominent fluorescence quenching interference on addition of various metal ions. The binding mode of PDA and Cu (II) ions was determined as stoichiometry of 1:1 and it was further confirmed by single crystal XRD analysis. Mechanisms of static and dynamic quenching were confirmed by stern–volmer plot. Limit of detection (LOD) and limit of quantification (LOQ …
Anahtar Kelimeler
Cu (II) ions | Job’s plot | Pyridine-2,6-dicarboxylic acid | Turn off fluorescent probe | XRD-structure