Insights into Supramolecular Networks Engineered via Tetrel and Hydrogen Bonding Interactions in Hemidirected Lead(II) Complexes
Yazarlar (8)
Tirtha Bhattacharjee
Independent Researcher, Hindistan
Independent Researcher, Hindistan
Sourav Nath
Govt. Degree College, Hindistan
Govt. Degree College, Hindistan
Subhadip Roy
Icfaı University Tripura, Hindistan
Icfaı University Tripura, Hindistan
Rosa M. Gomila
Universitat De Les Illes Balears, İspanya
Universitat De Les Illes Balears, İspanya
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Werner Kaminsky
University Of Washington, Amerika Birleşik Devletleri
University Of Washington, Amerika Birleşik Devletleri
Antonio Frontera
Universitat De Les Illes Balears, İspanya
Universitat De Les Illes Balears, İspanya
Suman Adhikari
Govt. Degree College, Hindistan
Govt. Degree College, Hindistan
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Crystal Growth and Design (Q1) | ||
| Dergi ISSN | 1528-7483 Dergi Bilgileri (2025) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2025 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 26-09-2025 |
| Cilt / Sayı / Sayfa | 25 / 20 / 8601–8615 | DOI | 10.1021/acs.cgd.5c00996 |
| Makale Linki | https://doi.org/10.1021/acs.cgd.5c00996 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| In this study, we explore the role of tetrel bonds (TtBs) and hydrogen bonds (H-bonds) in directing supramolecular crystal packing via self-assembly in two lead(II) chelates: [Pb(tren)(i-mnt)] (1) and [Pb4(tetraen)2(i-mnt)4] (2) [i-mnt–2 = 1,1-dicyanoethylene-2,2-dithiolate, tren = diethylene triamine, and tetraen = tris(2-aminoethyl)amine]. Both complexes were synthesized and isolated, and their solid-state structures were determined through single-crystal X-ray diffraction analysis. The secondary ligands (tren, tetraen) influence the coordination pattern of i-mnt–2 toward the Pb2+ center, generating diverse asymmetric geometries. Complex 1 is a vacant octahedral chelate, while complex 2 is a cocrystalline aggregate of crystallographically independent two cationic [Pb(tetraen)]+2 and two anionic [Pb(i-mnt)2]−2 inversion twins, each displaying seesaw geometry. These hemidirected lead(II) complexes with aliphatic … |
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| Web of Science | 7 |
| Scopus | 6 |
| Google Scholar | 7 |