The microwave assisted synthesis and structural characterization of novel dithia bridged polymeric phthalocyanines containing a substituted thiophenylamine Schiff base
Yazarlar (4)
Ismail Deǧirmencioǧlu
Karadeniz Technical University, Türkiye
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Öğr. Gör. Mustafa Er Karabük Üniversitesi, Türkiye
Prof. Dr. Kerim Serbest Recep Tayyip Erdogan University, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Dyes and Pigments (Q1)
Dergi ISSN 0143-7208 Dergi Bilgileri (2009)
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 10-2009
Cilt / Sayı / Sayfa 83 / 1 / 51–58 DOI 10.1016/j.dyepig.2009.03.011
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0143720809000631
UAK Araştırma Alanları
Anorganik Kimya
Özet
Novel polymeric metal-free and metallo(Cu(II), Co(II), Ni(II), Zn(II) and Pb(II))–phthalocyanine complexes were synthesized using microwave irradiation and the products were purified by several (crystallization and preparative thin layer) techniques. The newly prepared compounds were characterized by a combination of elemental analyses, IR, 1H/13C NMR, 1H–1H COSY, MS and UV–Vis spectroscopy. In order to better understand the spectroscopy data (especially for 1H/13C NMR and 1H–1H COSY techniques), computational calculations were used for characterization at DFT/6-31G(d) level. The electronic spectra exhibited an intense π → π* transition with characteristic Q and B bands of the phthalocyanine core.
Anahtar Kelimeler
Microwave-assisted | Phthalodinitrile | Polymeric phthalocyanines | Spectroscopic identification | Substituted Schiff base | Synthesis