Recent progress in Ni and Al-containing layered double hydroxides for dry reforming of methane
Yazarlar (4)
Dr. Öğr. Üyesi Zehra Betül ÖCAL Sinop Üniversitesi, Türkiye
Tannaz Sadeghi Rad
Faculty Of Pharmacy
Prof. Dr. Alıreza Khataee Istanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Ahmet Karagündüz Gebze Teknik Üniversitesi, Türkiye
Makale Türü Diğer (Teknik, not, yorum, vaka takdimi, editöre mektup, özet, kitap krıtiği, araştırma notu, bilirkişi raporu ve benzeri) (SCI, SSCI, AHCI, SCI-Exp dergilerinde yayınlanan teknik not, editöre mektup, tartışma, vaka takdimi ve özet türünden makale)
Dergi Adı Chemical Engineering Research and Design (Q2)
Dergi ISSN 0263-8762 Dergi Bilgileri (2025)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 06-2025
Kabul Tarihi Yayınlanma Tarihi 01-06-2025
Cilt / Sayı / Sayfa 218 / 1 / 619–633 DOI 10.1016/j.cherd.2025.05.016
Makale Linki https://www.sciencedirect.com/science/article/pii/S0263876225002485?dgcid=coauthor
UAK Araştırma Alanları
Nanoteknoloji
Özet
Layered double hydroxides (LDHs)-based catalysts containing NiAl have been widely used and investigated for years due to their high conversion efficiency, high basicity, and low coke formation as an alternative to noble metals in the dry reforming of methane (DRM) processes. Due to the synergetic effect between Ni and Al, there is a significant potential for the development of these catalysts. Hence, the impact of NiAl-LDH-based LDHs and the related parameters are reviewed on DRM processes. Different metals have been incorporated into the NiAl-LDH structure to enhance its effectiveness and to extend its durability for prolonged use. Various studies have claimed that the increase in the Ni/M ratio positively affects the DRM and Mg, Ce, La and Y are the frequently used metals to provide the catalytic effect, especially on the NiAl-LDH. Despite the constructive achieved developments, further enhancements are still required to address issues such as the decline in activity and limited lifespan of these catalysts. In this review, comprehensive information is given on the preparation techniques of LDHs and effects of preparation techniques on the characteristics and structural properties of NiAl-LDHs. In addition, the use of NiAl-LDHs in DRM processes and metal additives that will create a synergistic effect to increase catalytic performance and extend lifespan are discussed. Furthermore, the influences of operating conditions on catalytic performance, activity losses, and reaction mechanisms are reviewed. Finally, current developments and possible improvements are discussed.
Anahtar Kelimeler
Aluminum | Dry reforming | Layered materials | Methane | Nickel
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 3
Scopus 3
Recent progress in Ni and Al-containing layered double hydroxides for dry reforming of methane

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