Synthesis characterization and spectroscopic studies of novel peripherally tetra imidazole substituted phthalocyanine and its metal complexes the computational and experimental studies of the novel phthalonitrile derivative

Akçay, Hakk Türker; BAYRAK, RIZA; Karslioǧlu, Selami; Şahin, Ertan

doi:10.1016/j.jorganchem.2012.03.016

Synthesis characterization and spectroscopic studies of novel peripherally tetra imidazole substituted phthalocyanine and its metal complexes the computational and experimental studies of the novel phthalonitrile derivative

Yazarlar (4)

Hakk Türker Akçay
Karadeniz Technical University, Türkiye

Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye

Selami Karslioǧlu
Karadeniz Technical University, Türkiye

Prof. Dr. Ertan Şahin Atatürk Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Journal of Organometallic Chemistry (Q2)
Dergi ISSN	0022-328X Dergi Bilgileri (2012)
Dergi Tarandığı Indeksler	SCI
Makale Dili	İngilizce	Basım Tarihi	08-2012
Cilt / Sayı / Sayfa	713 / 1 / 1–10	DOI	10.1016/j.jorganchem.2012.03.016
Makale Linki	http://www.sciencedirect.com/science/article/pii/S0022328X12001623
UAK Araştırma Alanları	Anorganik Kimya

Özet

Compound (3) was synthesized by the reaction of 4-(4,5-diphenyl-1H- imidazol-2-yl) phenol and 4-nitrophthalonitrile in dry DMF in presence of K 2CO 3 and obtained as single crystal form suitable for x-ray analysis. Vibrational assignments and electronic transitions of the compound (3) were calculated and compared with the experimental results. Compound (4) was obtained from compound (33), by heating at 160 °C for 24 h under N 2 atmosphere in dry N,N dimethyl aminoethanol. Compounds (5-8) were synthesized by the same method applied for the synthesis of compound (4) with addition of the corresponding metal salts (ZnCH 3COO 2, NiCl 2, CoCl 2, CuCl 2). Prepared phthalocyanines were purified by column chromotography using appropriate solvent system and characterized by elemental analysis ¹H NMR, ¹³C NMR, UV-vis, IR and mass spectra. Aggregation behavior of compound (5) was studied in different solvents and different concentrations in DMSO. In addition, protonation behavior of the compound (5) was investigated in different mixtures of sulfuric acid and DMSO. © 2012 Elsevier B.V. All rights reserved.

Anahtar Kelimeler

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Web of Science	28
Scopus	28

Synthesis characterization and spectroscopic studies of novel peripherally tetra imidazole substituted phthalocyanine and its metal complexes the computational and experimental studies of the novel phthalonitrile derivative

Dergi Adı	JOURNAL OF ORGANOMETALLIC CHEMISTRY
Kısa Adı	J ORGANOMET CHEM
Yayıncı	ELSEVIER SCIENCE SA
Açık Erişim	Hayır
ISSN	0022-328X
E-ISSN	1872-8561
Wos Quartile	Q2
Scopus Quartile	Q1
Tarandığı Indeksler	SCIE , Scopus
WoS Kategoriler	CHEMISTRY, INORGANIC & NUCLEAR \| CHEMISTRY, ORGANIC
Scopus Kategoriler	MATERIALS CHEMISTRY \| BIOCHEMISTRY \| INORGANIC CHEMISTRY \| ORGANIC CHEMISTRY \| PHYSICAL AND THEORETICAL CHEMISTRY

Synthesis characterization and spectroscopic studies of novel peripherally tetra imidazole substituted phthalocyanine and its metal complexes the computational and experimental studies of the novel phthalonitrile derivative

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