Synthesis electrochemical and spectroelectrochemical properties of peripherally tetra imidazole substituted metal free and metallophthalocyanines
Yazarlar (6)
Hakki Türker Akçay Karadeniz Technical University, Türkiye
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Prof. Dr. Ümit Demirbaş Karadeniz Technical University, Türkiye
Atif Koca Marmara Üniversitesi, Türkiye
Prof. Dr. Halit Kantekin Karadeniz Technical University, Türkiye
Ismail Deǧirmencioǧlu
Karadeniz Technical University, Türkiye
Karadeniz Technical University, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Dyes and Pigments (Q1) | ||
| Dergi ISSN | 0143-7208 Dergi Bilgileri (2013) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2013 |
| Cilt / Sayı / Sayfa | 96 / 2 / 483–494 | DOI | 10.1016/j.dyepig.2012.09.005 |
| Makale Linki | http://www.sciencedirect.com/science/article/pii/S0143720812002628 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| The synthesis and characterization of novel organosoluble peripherally tetra imidazole substituted metal-free (4), zinc(II) (5), nickel(II) (6), cobalt(II) (7), lead(II) (8) and oxo-titanium(IV) (9) phthalocyanines are described for the first time in this study. Electrochemical and spectroelectrochemical measurements exhibit that while copper phthalocyanine gives only ring-based electron transfer reactions, incorporating redox active metal centers, Co(II), and Ti(IV)OPc, into the phthalocyanine core extends the redox richness of the phthalocyanine ring with the metal-based reduction and oxidation couples of the metal centers in addition to the common phthalocyanine ring-based electron transfer processes. In-situ electrocolorimetric measurements of the complexes allow quantification of color coordinates of the each electrogenerated anionic and cationic redox species. |
| Anahtar Kelimeler |
| Electrochemistry | Imidazole | Phthalocyanine | Soluble | Spectroelectrochemistry | Synthesis |
Science Direct
Synthesis electrochemical and spectroelectrochemical properties of peripherally tetra imidazole substituted metal free and metallophthalocyanines
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 39 |
| Scopus | 42 |
| Google Scholar | 45 |