Novel triazole bearing zinc II and magnesium II metallo phthalocyanines Synthesis characterization photophysical and photochemical properties
Yazarlar (7)
Prof. Dr. Hakkı Türker Akçay Recep Tayyip Erdoğan Üniversitesi, Türkiye
Prof. Dr. Mehmet Pişkin Çanakkale Onsekiz Mart Üniversitesi, Türkiye
Prof. Dr. Ümit Demirbaş Karadeniz Teknik Üniversitesi, Türkiye
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Mahmut Durmuş Gebze Teknik Üniversitesi, Türkiye
Prof. Dr. Emre Menteşe Recep Tayyip Erdoğan Üniversitesi, Türkiye
Prof. Dr. Halit Kantekin Karadeniz Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Organometallic Chemistry (Q2)
Dergi ISSN 0022-328X Dergi Bilgileri (2013)
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 11-2013
Cilt / Sayı / Sayfa 745 / 1 / 379–386 DOI 10.1016/j.jorganchem.2013.08.029
Makale Linki http://www.sciencedirect.com/science/article/pii/S0022328X13006517
UAK Araştırma Alanları
Anorganik Kimya
Özet
The synthesis and characterization of novel tetrakis N-(3,5-dichlorophenyl)-5-methyl-3H-1,2,4-triazol-3-one (1) and N-(3,5-dichlorophenyl)-5-ethyl-3H-1,2,4-triazol-3-one (2) substituted phthalonitrile derivatives and their new organosoluble peripherally tetra-substituted zinc(II) (6 and 7) and magnesium(II) (8 and 9) phthalocyanines were studied in this study. Photophysical and photochemical data of these compounds were measured in dimethysulfoxide (DMSO). The magnesium(II) phthalocyanine derivatives showed excellent fluorescent properties and the corresponding zinc(II) phthalocyanines generated efficient singlet oxygen. The fluorescence quenching behavior of the studied tetra-peripherally substituted zinc(II) and magnesium(II) phthalocyanine compounds by the addition of 1,4-benzoquinone were also studied in DMSO. These molecules can distinctly be employed in the field of photodynamic therapy in …
Anahtar Kelimeler
Fluorescence | Magnesium | Phthalocyanine | Singlet oxygen | Triazole | Zinc