The determination of photophysical and photochemical parameters of novel metal free zinc II and lead II phthalocyanines bearing 1 2 4 triazole groups
Yazarlar (7)
Prof. Dr. Ümit Demirbaş Karadeniz Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Pişkin Çanakkale Onsekiz Mart Üniversitesi, Türkiye
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Dilek Ünlüer
Karadeniz Technical University, Türkiye
Esra Düğdü
Karadeniz Technical University, Türkiye
Mahmut Durmuş Gebze Teknik Üniversitesi, Türkiye
Prof. Dr. Halit Kantekin Karadeniz Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Synthetic Metals (Q2)
Dergi ISSN 0379-6779 Dergi Bilgileri (2016)
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 05-2016
Kabul Tarihi Yayınlanma Tarihi 01-09-2016
Cilt / Sayı / Sayfa 219 / 1 / 76–82 DOI 10.1016/j.synthmet.2016.05.008
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0379677916301485
UAK Araştırma Alanları
Anorganik Kimya
Özet
In this study the synthesis and characterization of novel phthalonitrile compound (3) and its metal-free (4), zinc(II) (5), and lead(II) (6) phthalocyanines bearing four 4-(4-methoxyphenylethyl)-5-propyl-2,4-dihydro-3H-1,2,4-triazol-3-one groups at peripheral positions were synthesized for the first time. These novel compounds were fully characterized by FT-FT-IR, 1H NMR, UV–vis and MALDI-TOF mass spectroscopic techniques. Their photochemical and photophysical properties were also investigated in N,N-dimethylformamide solutions. In addition, the effect of 4-(4-methoxyphenylethyl)-5-propyl-2,4-dihydro-3H-1,2,4-triazol-3-one groups as substituents and central metal ions (without metal, zinc(II) or lead(II)) in the phthalocyanine cavity on these properties were also compared. The studied zinc(II) or lead(II) phthalocyanines can be potential Type II photosensitizers for photodynamic therapy in cancer applications …
Anahtar Kelimeler
Lead | Metal-free | Photochemical | Photophysical | Phthalocyanine | Zinc