Metal free zinc II and lead II phthalocyanines functioning with 3 2H benzo d 1 2 3 triazol 2 yl 4 hydroxyphenethyl methacrylate groups Synthesis and investigation of photophysical and photochemical properties
Yazarlar (6)
Prof. Dr. Ümit Demirbaş Karadeniz Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Pişkin Çanakkale Onsekiz Mart Üniversitesi, Türkiye
Doç. Dr. Burak Barut Karadeniz Teknik Üniversitesi, Türkiye
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Mahmut Durmuş Gebze Teknik Üniversitesi, Türkiye
Prof. Dr. Halit Kantekin Karadeniz Teknik Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Synthetic Metals (Q2) | ||
| Dergi ISSN | 0379-6779 Dergi Bilgileri (2016) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2016 |
| Cilt / Sayı / Sayfa | 220 / 1 / 276–285 | DOI | 10.1016/j.synthmet.2016.06.026 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S0379677916302193 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| In this study, the synthesis and characterization of 3-(2H-benzo[d][1,2,3]triazol-2-yl)-4-hydroxyphenethyl methacrylate substituted novel phthalonitrile compound and its peripherally substituted zinc(II) lead(II) and metal-free phthalocyanine derivatives were performed for the first time. This novel compounds were characterized by obtained data from general spectroscopic methods such as FT-IR, 1H NMR, 13C NMR and mass. The photophysical and photochemical properties of these phthalocyanines were investigated in N,N-dimethylformamide solutions for determination of their photosensitizing abilities in photocatalytic applications such as photodynamic therapy. The lead(II) phthalocyanine complex did not produce any fluorescent in N,N-dimethylformamide because of the heavy atom effect of bigger lead atom. The fluorescence quantum yields of studied zinc(II) and metal-free phthalocyanines were found to quite higher than unsubstituted zinc(II) phthalocyanine due to substitution of the phthalocyanine skeleton. The influence of substituent and variety of the central metal ions on spectroscopic, photophysical and photochemical properties were also determined and compared. |
| Anahtar Kelimeler |
| Benzotriazole | Photochemical | Photophysical | Photosensitizer | Phthalocyanine |
Science Direct
Metal free zinc II and lead II phthalocyanines functioning with 3 2H benzo d 1 2 3 triazol 2 yl 4 hydroxyphenethyl methacrylate groups Synthesis and investigation of photophysical and photochemical properties
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 35 |
| Scopus | 36 |