Electrochemical and spectroelectrochemical properties of thiadiazole substituted metallo phthalocyanines
 
Yazarlar (6)
Prof. Dr. Ümit Demirbaş Karadeniz Teknik Üniversitesi, Türkiye
Dr. Öğr. Üyesi Duygu Akyüz Marmara Üniversitesi, Türkiye
Doç. Dr. Burak Barut Karadeniz Teknik Üniversitesi, Türkiye
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Prof. Dr. Atıf Koca Marmara Üniversitesi, Türkiye
Prof. Dr. Halit Kantekin Karadeniz Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy (Q2)
Dergi ISSN 1386-1425 Dergi Bilgileri (2016)
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 08-2016
Cilt / Sayı / Sayfa 153 / 1 / 71–78 DOI 10.1016/j.saa.2015.07.105
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S1386142515301529
UAK Araştırma Alanları
Anorganik Kimya
Özet
4-Thiadiazole substituted phthalonitrile and peripherally tetra-substituted phthalocyanine Cu(II), Fe(II) and Ti(IV)O complexes have been synthesized for the first time. Electrochemical properties of these complexes were determined with voltammetric and in situ spectroelectrochemical measurements. CuPc has redox inactive Cu2 + center, therefore it gave three Pc based reduction and two Pc based oxidation processes. TiOPc and FePc complexes gave metal based redox processes in addition to Pc based redox reactions due to the redox activity of Ti4 +O and Fe2 + metal centers. Although FePc also gave three reduction and two oxidation reactions, peak potentials of these processes are different than those of CuPc due to the different assignments of the redox reactions. TiOPc went to five reduction and one oxidation reactions. Assignments of the redox processes were carried out with in situ spectroelectrochemical …
Anahtar Kelimeler
Electrochemistry | Metallophthalocyanine | Phthalocyanine | Spectroelectrochemistry | Thiadiazole
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 31
Scopus 31
Google Scholar 38
Electrochemical and spectroelectrochemical properties of thiadiazole substituted metallo phthalocyanines

Paylaş