The synthesis and structural characterization of new metallophthalocyanines with 1 24 triazole fragments
Yazarlar (4)
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Prof. Dr. Olcay Bekircan Karadeniz Technical University, Türkiye
Prof. Dr. Mahmut Durmuş Gebze Teknik Üniversitesi, Türkiye
Ismail Deǧirmencioǧlu
Karadeniz Technical University, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Organometallic Chemistry (Q2)
Dergi ISSN 0022-328X Dergi Bilgileri (2014)
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 06-2014
Cilt / Sayı / Sayfa 767 / 1 / 101–107 DOI 10.1016/j.jorganchem.2014.06.003
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0022328X14002903
UAK Araştırma Alanları
Anorganik Kimya
Özet
Novel Zn(II), Ni(II), Co(II) and Cu(II) phthaloyanine complexes that have [1,2,4]-triazole and Schiff's base moieties on peripheral positions have been synthesized. Key material, substituted phthalonitrile, was obtained in four-step reaction. Firstly hydrazone derivative has been obtained, then [1,2,4]-triazole moiety has been created, Schiff base fragment has been constituted and then phthalonitrile fragment has been added to the structure. The novel phthalocyanines are soluble in many organic solvents. The photophysical, photochemical and fluorescence quenching properties of zinc phthalocyanine derivative (10) have been studied in dimethylsulfoxide (DMSO) solution. These properties of the other metallophthalocyanine complexes (11, 12 and 13) have not been appreciated because zinc phthalocyanine is the best compound for photocatalytic applications due to the d10 configuration of the Zn2+ ion in the …
Anahtar Kelimeler
Metallophthalocyanine | Photochemistry | Photophysic | Phthalocyanine | Schiff base | Triazole
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 23
Scopus 22
Google Scholar 25
The synthesis and structural characterization of new metallophthalocyanines with 1 24 triazole fragments

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