DBU catalyzed condensation of metal free and metallophthalocyanines containing thiazole and azine moieties Synthesis characterization and electrochemical properties
Yazarlar (5)
Gökhan Dede
Marmara Üniversitesi, Türkiye
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Öğr. Gör. Mustafa Er Karabük Üniversitesi, Türkiye
Ali Ryza Özkaya
Marmara Üniversitesi, Türkiye
Ismail Deǧirmencioǧlu
Karadeniz Technical University, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Organometallic Chemistry (Q2)
Dergi ISSN 0022-328X Dergi Bilgileri (2013)
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 04-2013
Cilt / Sayı / Sayfa 740 / 1 / 70–77 DOI 10.1016/j.jorganchem.2013.04.043
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0022328X13003495
UAK Araştırma Alanları
Anorganik Kimya
Özet
Schiff base that contains carbothioamide moiety, substituted thiazole derivative, novel phthalonitrile compound and its corresponding metal free and metal phthalocyanines (Zn(II), Ni(II), Co(II) and Cu(II)) were synthesized and characterized for the first time. The solubility of these novel phthalocyanines were high in organic solvents and they did not aggregate in chloroform within the concentration range of 1.6 × 10−5–4 × 10−6 M. Electrochemical properties of the phthalocyanines have been examined by cyclic voltammetry, square wave voltammetry and in situ UV–vis spectroelectrochemistry on Pt in dimethylsulfoxide/tetrabutylammonium perchlorate. These measurements suggested that the compounds display subsequent ligand- and/or metal-based one-electron reduction and oxidation processes. Cobalt complex showed both metal-based and ring-based one-electron redox processes, while the other complexes …
Anahtar Kelimeler
Azine | Electrochemistry | Phthalocyanine | Synthesis | Thiazole