Peripherally and non-peripherally tetra-benzothiazole substitutedmetal-free zinc (II) and lead (II) phthalocyanines: Synthesis,characterization, and investigation of photophysical andphotochemical properties

Demirbaş, Ümit; Göl, Cem; Barut, Burak; BAYRAK, RIZA; Durmuş, Mahmut; Kantekin, Halit; Değirmencioğlu, İsmail

doi:10.1016/j.molstruc.2016.11.017

Peripherally and non-peripherally tetra-benzothiazole substitutedmetal-free zinc (II) and lead (II) phthalocyanines: Synthesis,characterization, and investigation of photophysical andphotochemical properties

Yazarlar (7)

Prof. Dr. Ümit Demirbaş Karadeniz Technical University, Türkiye

Dr. Öğr. Üyesi Cem Göl Abant İzzet Baysal Üniversitesi, Türkiye

Doç. Dr. Burak Barut Karadeniz Teknik Üniversitesi, Türkiye

Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye

Mahmut Durmuş Gebze Teknik Üniversitesi, Türkiye

Prof. Dr. Halit Kantekin Karadeniz Teknik Üniversitesi, Türkiye

Prof. Dr. İsmail Değirmencioğlu Karadeniz Teknik Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Journal of Molecular Structure (Q3)
Dergi ISSN	0022-2860 Dergi Bilgileri (2017)
Dergi Tarandığı Indeksler	SCI
Makale Dili	İngilizce	Basım Tarihi	01-2017
Cilt / Sayı / Sayfa	1130 / 1 / 677–687	DOI	10.1016/j.molstruc.2016.11.017
Makale Linki	https://linkinghub.elsevier.com/retrieve/pii/S0022286016311735
UAK Araştırma Alanları	Anorganik Kimya

Özet

In this study, novel phthalonitrile compounds bearing 2-methylbenzo[d]thiazol-5-yloxy groups (4 and 5) and their peripherally and non-peripherally tetra-substituted metal-free (6 and 7), zinc (II) (8 and 9), and lead (II) (10 and 11) phthalocyanine derivatives were synthesized and characterized for the first time. These novel compounds showed extremely good solubility in most common organic solvents. The novel phthalocyanine compounds presented excellent results from photophysical and photochemical examinations in DMF solution. Especially, the singlet oxygen quantum yield (ΦΔ) values of the substituted zinc (II) phthalocyanines indicate that these compounds have significant potential as photosensitizers in cancer treatment by the photodynamic therapy (PDT) technique. The fluorescence quenching behaviour of these novel phthalocyanine compounds by 1,4-benzoquinone (BQ) was also examined in DMF solution.

Anahtar Kelimeler

Benzothiazole | Fluorescence quenching | Photosensitizer | Phthalocyanine | Singlet oxygen

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Web of Science	37
Scopus	37

Peripherally and non-peripherally tetra-benzothiazole substitutedmetal-free zinc (II) and lead (II) phthalocyanines: Synthesis,characterization, and investigation of photophysical andphotochemical properties

Dergi Adı	JOURNAL OF MOLECULAR STRUCTURE
Kısa Adı	J MOL STRUCT
Yayıncı	ELSEVIER SCIENCE BV
Açık Erişim	Hayır
ISSN	0022-2860
E-ISSN	1872-8014
Wos Quartile	Q3
Scopus Quartile	Q3
Tarandığı Indeksler	SCIE , Scopus
WoS Kategoriler	CHEMISTRY, PHYSICAL
Scopus Kategoriler	ANALYTICAL CHEMISTRY \| INORGANIC CHEMISTRY \| ORGANIC CHEMISTRY \| SPECTROSCOPY

Peripherally and non-peripherally tetra-benzothiazole substitutedmetal-free zinc (II) and lead (II) phthalocyanines: Synthesis,characterization, and investigation of photophysical andphotochemical properties

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